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合成了钨铕杂多酸,并与丙烯酰胺单体通过水溶液聚合制备了钨铕杂多酸/聚丙烯酰胺薄膜材料(Eu W10/PAM).红外光谱表明EuW10/PAM聚合物膜中的钨铕杂多酸仍保持Keggin结构;荧光分析表明,EuW10/PAM呈现典型的Eu3+离子的特征荧光,而且经过多氧金属簇的敏化,呈现强的荧光性能.

参考文献

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[2] 许林,王恩波,胡长文.多金属氧酸盐作为构筑块自组装合成新型功能性分子材料[J].无机化学学报,2000(02):218-228.
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[5] M Sugeta;T Yamase .Crystal structure luminscence site of Na9[Eu W10 O36]@32H2O[J].Chem Soc Jpn,1993,66:444-449.
[6] 王力,王秀丽,侯煜,王恩波.多金属氧酸盐α-Na7H[GaW9Fe3(H2O)3O37]·16H2O合成和光谱[J].光谱学与光谱分析,2004(05):613-615.
[7] 余江,许振华,徐光宪,韩梅.新型铕(Ⅲ)、穴醚[2.2]与α-噻吩甲酰三氟丙酮三元荧光配合物的合成与表征[J].化学学报,1997(02):153-159.
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