阳极是限制海底微生物燃料电池输出功率的关键因素,通过改性阳极,可望提高微生物燃料电池性能.本文利用MnSO4氧化还原介体修饰石墨阳极,研究了MnSO4含量对阳极和电池产电性能的影响.结果表明,锰离子可有效加速电子转移,当阳极MnSO4的含量为4%时,阳极性能最好,电池内阻最小,最大输出功率密度为51.64mW/m2,是普通石墨电极的3倍.
参考文献
[1] | Bond D R;Holmes D E;Tender L M et al.Electrode-reducing microorganisms that harvest energy from marine sediments[J].Science,2002,295:483-485. |
[2] | Akyildiz I F;Pompili D;Melodia T .Underwater acoustic sensor networks:research challenges[J].Ad Hoc Networks Journal,2005,3:257-279. |
[3] | DeLong EF;Chandler P .Power from the deep[J].Nature biotechnology,2002(8):788-789. |
[4] | Rezaei F;Richard TL;Brennan RA;Logan BE .Substrate-enhanced microbial fuel cells for improved remote power generation from sediment-based systems[J].Environmental Science & Technology: ES&T,2007(11):4053-4058. |
[5] | Clare E. Reimers;Leonard M. Tender;Stephanie Fertig;Wei Wang .Harvesting energy from the marine sediment-water interface[J].Environmental Science & Technology: ES&T,2001(1):192-195. |
[6] | Tender LM;Reimers CE;Stecher HA;Holmes DE;Bond DR;Lowy DA .Harnessing microbially generated power on the seafloor[J].Nature biotechnology,2002(8):821-825. |
[7] | 冯雅丽,李浩然,连静,周良.利用微生物电池研究微生物在矿物表面电子传递过程[J].北京科技大学学报,2006(11):1009-1013. |
[8] | Logan Bruce E.Microbial Fuel Cells[M].Hoboken Inc:John Wiley & Sons,2008:62-68. |
[9] | 李旭光,邢巍,杨辉,陆天虹.活性炭载体对聚合物电解质膜燃料电池中炭载铂电催化剂性能的影响[J].分析化学,2002(07):788-791. |
[10] | Lowy DA;Tender LM;Zeikus JG;Park DH;Lovley DR .Harvesting energy from the marine sediment-water interface II - Kinetic activity of anode materials[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,2006(11):2058-2063. |
[11] | Park Doo Hyun .Electricity production in biofuel cell using modified graphite electrode with Neutral Red[J].Biotechnology Letters,2000(16):1301-1304. |
[12] | 詹姆斯;安德鲁.燃料电池系统--原理,设计,应用[M].北京:科学出版社,2006:35-52. |
[13] | 梁鹏,范明志,曹效鑫,黄霞,王诚.微生物燃料电池表观内阻的构成和测量[J].环境科学,2007(08):1894-1898. |
[14] | Bond, DR;Lovley, DR .Evidence for involvement of an electron shuttle in electricity generation by Geothrix fermentans[J].Applied and Environmental Microbiology,2005(4):2186-2189. |
[15] | Uwe Schroder .Anodic electron transfer mechanisms in microbial fuel cells and their energy efficiency[J].Physical chemistry chemical physics: PCCP,2007(21):2619-2629. |
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