几种有机酸对广东共和花岗岩风化壳样品中稀土元素的浸泡实验结果表明:①稀土的浸出量随酸浓度的增加而明显升高;②低浓度的有机酸对稀土的浸出量随着水岩比的增加而增加;③有机酸与风化壳样品的作用结果导致介质的pH值会发生变化,大多数是pH值升高;稀土的浸出量随着pH降低有升高的趋势;④与硫酸铵所浸出的稀土相比,有机酸对风化壳稀土的浸出结果是Ce负异常减弱,Eu负异常增加,(La/Sm)N和(Gd/Yb)N比值相对减少,即有机酸对风化壳稀土分异作用作出了贡献.
参考文献
[1] | 王中刚;于学元;赵振华.稀土元素地球化学[M].北京:科学出版社,1989:321-342. |
[2] | 吴澄宇;黄典豪;郭中勋 .江西龙南花岗岩风化壳中稀土元素的地球化学研究[J].地质学报,1989,63(04):349-362. |
[3] | GOUVEIA M A;Prudencio M I;Figueiredo M O et al.Behaviour of REE and other trace and major elements during weathering of granitic rocks[J].Evora Portugal Chem Geol,1993,107:293-296. |
[4] | Minarik L.;Bendl J.;Skrivan P.;St'astny M.;Zigova A. .The behaviour of rare-earth elements and Y during the rock weathering and soil formation in the Ricany granite massif, Central Bohemia[J].Science of the Total Environment,1998(1/2):101-111. |
[5] | Chen Zhicheng,Yu Shoujun,Fu Qunce,Chen Binghui,Zhang Lijie.Organic Metallogeny of Weathering Crust RE Deposit[J].中国稀土学报,1998(01):59-67. |
[6] | A.E.Taunton;S.A.Welch .Geomicrobiological controls on light rare earth element, Y and Ba distributions during granite weathering and soil formation[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(0):30-36. |
[7] | Chen Binghui;Wang Zhimei;Huang Limei et al.The microbial metallogeny of weathering crust REE deposits in South China[J].科学通报(英文版),1999(44):71-73. |
[8] | EHRLISH H L.Geomicrobiology:Its Significance For Geology[M].Earth-Science Reviews,1998:45-60. |
[9] | 某些常用稀土元素地球化学参数的计算方法及其地球化学意义[J].地质地球化学,1985(z1):11-14. |
[10] | 杨学明.江西大吉山花岗岩风化壳稀土矿床稀土元素地球化学[J].稀土,1999(01):1. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%