在乙醇和水的混合溶剂中,合成了均苯四甲酸铽发光配合物.通过元素分析、化学分析、红外光谱、热分析等确定其化学组成为 Tb(HL)·5H2O.X射线衍射分析表明配合物为晶体物质,扫描电镜照片结果表明配合物为棒状物质,晶粒大小10μm~20μm,荧光光谱分析表明配合物在紫外光的激发下发出铽的特征荧光.
参考文献
[1] | Ping Liu;Dong Liang;Zhen Tong et al.Synthesis and luminescence properties of novel europium and terbium complexes with triblock copolymer ligand[J].Macromolecules,2002,35:1487-1488. |
[2] | Christine L;Maupin;Anna Mondry et al.Pressure and temperature dependence of the 7F0→5D0 excitation spectrum of europium(Ⅲ) as a probe of the thermodynamics and solution structure of complexes of europium(Ⅲ) with polyaminocarboxylate ligands[J].Journal of Physical Chemistry A Molecules Spectroscopy Kinetics Environment and General Theory,2001,105:3071-3076. |
[3] | Quan Li;Tao Li;Jinguang Wu .Luminescence of europium(Ⅲ) and terbium(Ⅲ) complexes incorporated in poly(vinyl pyrrolidone) matrix[J].Journal of Physical Chemistry B,2001,105:12293-12296. |
[4] | Shi Huahong;Yang Yansheng .Synthesis,characterization and luminescent properties of Eu(Ⅲ) and Tb(Ⅲ) fluorescent chelates used as label in medical immunoassays[J].Journal of Alloys and Compounds,1994,207-208:29-32. |
[5] | 雷衡毅;杨燕生;孟建新 等.化学修饰生长素及其性质研究Ⅱ.含Ca(Ⅱ),Al(Ⅲ),RE(Ⅲ) 离子的Tb(Ⅲ)--乙酰丙酮基吲哚酸体系的荧光性能研究[J].中山大学学报论丛,1995,1(01):174-180. |
[6] | 邢彦;金钟声;段治邦 等.1,2,4,5-苯甲酸铒配合物的合成及晶体结构[J].化学学报,1987,45:1044-1047. |
[7] | Cao R.;Sun DF.;Liang YC.;Hong MC.;Tatsumi K.;Shi Q. .Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2002(8):2087-2094. |
[8] | 赵学辉,彭红建,毛向辉.均苯四甲酸-三苯基氧化膦-铽-钇配合物的高效发光[J].光谱实验室,1999(02):117-119. |
[9] | 尹洪宗,曲祥金,周杰,朱贵云,司志坤.铽-镧(镥、钇)-均苯四甲酸共发荧光体系的研究和应用[J].分析试验室,1998(04):44. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%