综述了稀土氧化物和稀土离子对直接醇类燃料电池催化剂的修饰助催化作用,以及含稀土的钙钛矿型氧化物在直接醇类燃料电池中的应用,阐述了它们各自的催化或助催化作用机理,并对它们在直接醇类燃料电池中的应用前景进行了展望.
参考文献
| [1] | Yang Liu;Xiaofeng Xie;Yuming Shang .Power characteristics and fluid transfer in 40 W direct methanol fuel cell stack[J].Journal of Power Sources,2007(1):322-327. |
| [2] | 吴韬,齐亮,郭建伟,王要武,谢晓峰,唐有根,陈昊.直接甲醇燃料电池在军事领域上的应用[J].兵工自动化,2007(01):79-80,88. |
| [3] | 陆天虹,唐亚文,刘长鹏,邢巍.小型燃料电池商品化展望[J].电池工业,2005(06):361-363. |
| [4] | Liu, ZL;Hong, L .Electrochemical characterization of the electrooxidation of methanol, ethanol and formic acid on Pt/C and PtRu/C electrodes[J].Journal of Applied Electrochemistry,2007(4):505-510. |
| [5] | A.O. NETO;T.R.R. VASCONCELOS;R.W.R.V.D. SILVA .Electrooxidation of ethylene glycol on PtRu/C and PtSn/C electrocatalysts prepared by alcohol-reduction process[J].Journal of Applied Electrochemistry,2005(2):193-198. |
| [6] | Zhang LL;Lu TH;Bao JC;Tang YW;Li C .Preparation method of an ultrafine carbon supported Pd catalyst as an anodic catalyst in a direct formic acid fuel cell[J].Electrochemistry communications,2006(10):1625-1627. |
| [7] | Ha S;Larsen R;Masel R I .Performance characterization of Pd/C nanocatalyst for direct formic acid fuel cells[J].Journal of Power Sources,2005,144:28-34. |
| [8] | 章冬云,马紫峰,原鲜霞.乙醇电催化氧化反应动力学分析与研究进展[J].化工进展,2005(02):126-131. |
| [9] | L. Colmenares;H. Wang;Z. Jusys;L. Jiang;S. Yan;G. Q. Sun;R. J. Behm .Ethanol oxidation on novel, carbon supported Pt alloy catalysts - Model studies under defined diffusion conditions[J].Electrochimica Acta,2006(1):221-233. |
| [10] | Yuqin Xu;Xiaofeng Xie;Jianwei Guo .Effects of annealing treatment and pH on preparation of citrate-stabilized PtRu/C catalyst[J].Journal of Power Sources,2006(1):132-140. |
| [11] | 孙芳,邬冰,李桂春,高颖,陆天虹,刘长鹏,邢巍.乙醇和CO在Pt-WO3/C电极上的电催化氧化[J].分子科学学报,2006(04):215-218. |
| [12] | 森利之;高桥基;西村睦 .Pt/CeO2/(道)/(寸)电性碳素ナノヘテロアノ一ド材料およびその(制)/(衣)造方法[P].WO 2006006739 A1,2006-01-19. |
| [13] | Kyung-Won Park;Yung-Eun Sung;Jong-Ho Choi;Seol-Ah Lee;Chanho Pak;Hyuk Chang .PtRuRhNi nanoparticle electrocatalyst for methanol electrooxidation in direct methanol fuel cell[J].Journal of Catalysis,2004(2):236-242. |
| [14] | Antolini E;Salgado J R C;Gonzalez E R .The stability of Pt M (M = first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells[J].Journal of Power Sources,2006,160:957-968. |
| [15] | Thiago Lopes;Ermete Antolini;Flavio Colmati .Carbon supported Pt-Co (3:1) alloy as improved cathode electrocatalyst for direct ethanol fuel cells[J].Journal of Power Sources,2007(1):111-114. |
| [16] | 郭耘,卢冠忠.稀土催化材料的应用及研究进展[J].中国稀土学报,2007(01):1-15. |
| [17] | Esch, F;Fabris, S;Zhou, L;Montini, T;Africh, C;Fornasiero, P;Comelli, G;Rosei, R .Electron localization determines defect formation on ceria substrates[J].Science,2005(5735):752-755. |
| [18] | Gritschneder S;Iwasawa Y;Reichling M .Strong adhesion of water to CeO2(111)[J].Nanotechnology,2007(26):44025-1-44025-6-0. |
| [19] | Xu CW;Shen PK .Novel Pt/CeO2/C catalysts for electrooxidation of alcohols in alkaline media[J].Chemical communications,2004(19):2238-2239. |
| [20] | Xu C W;Shen P K .Electrochamical oxidation of ethanol on Pt-CeO2/C catalysts[J].Journal of Power Sources,2005,142:27-29. |
| [21] | 徐常威,田植群,沈培康.甘油和乙醇在Pt-CeO2/C电极上的氧化[J].电池,2004(03):212-214. |
| [22] | Gou J W;Zhao T S;Prabhuram J et al.Development of PtRu-CeO2/C anode electrocatalyst for direct methanol fuel cells[J].Journal of Power Sources,2006,156:345-354. |
| [23] | Wang J S;Deng X Z;Xi J Y et al.Promoting the current for methanol electro-oxidation by mixing Pt-based catalysts with CeO2 nanoparticles[J].Journal of Power Sources,2007,170:297-302. |
| [24] | Wang J S;Xi J Y;Bai Y X et al.Structural designing of Pt-CeO2/CNTs for methanol electro-oxidation[J].Journal of Power Sources,2007,164:555-560. |
| [25] | Huang SY;Chang CM;Yeh CT .Promotion of platinum-ruthenium catalyst for electro-oxidation of methanol by ceria[J].Journal of Catalysis,2006(2):400-406. |
| [26] | Campos CL;Roldan C;Aponte M;Ishikawa Y;Cabrera CR .Preparation and methanol oxidation catalysis of Pt-CeO2 electrode[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2005(2):206-215. |
| [27] | Yu H B;Kim J H;Lee H I et al.Development of nanophase CeO2-Pt/C cathode catalyst for direct methanol fuel cell[J].Journal of Power Sources,2005,140:59-65. |
| [28] | 陈玲,王新东,郭敏.NdOx作为助催化剂对PtRu/C电催化氧化甲醇活性的影响[J].物理化学学报,2006(02):141-145. |
| [29] | 陈玲,王新东,郭敏.DMFC的PtRu-NdOx/C催化剂合成及性能[J].电源技术,2006(06):439-442. |
| [30] | Chen L;Guo M;Zhang H F et al.Characterization and electrocatalytic properties of PtRu/C catalysts prepared by impregnation-reduction method using Nd2O3 as dispersing reagent[J].Electrochimica Acta,2006,52:1191-1198. |
| [31] | Zhicheng Tang;Gongxuan Lu .High performance rare earth oxides LnO_x (Ln = Sc, Y, La, Ce, Pr and Nd) modified Pt/C electrocatalysts for methanol electrooxidation[J].Journal of Power Sources,2006(2):1067-1072. |
| [32] | 高颖,邬冰,万丽娟,刘长鹏,邢巍,陆天虹.Ho3+对吸附CO电化学氧化的促进作用[J].物理化学学报,2004(09):1108-1111. |
| [33] | 高颖,邬冰,刘长鹏,唐亚文,邢巍,陆天虹.吸附在Pt/C催化剂上Eu3+对CO电氧化的促进作用[J].无机化学学报,2004(11):1344-1348. |
| [34] | 邬冰,乔英杰,高颖,万丽娟,刘长鹏,邢巍,陆天虹.稀土修饰电极Pt - TiO2/Eu3+/C对CO电氧化的影响[J].哈尔滨工业大学学报,2005(05):658-660. |
| [35] | 万丽娟,高颖,邬冰,刘长鹏,邢巍,陆天虹.Eu3+和Ho3+对乙醇在Pt-TiO2/C电极上氧化的助催化作用[J].物理化学学报,2004(06):616-620. |
| [36] | 杜秉忱,刘晶华,薛新忠,徐维林,邢巍,陆天虹,桑革.Sm3+对甲醇电化学氧化反应的助催化作用[J].高等学校化学学报,2004(05):917-921. |
| [37] | 冉锐,吴晓东,翁端.稀土钙钛矿催化剂制备方法的研究进展[J].稀土,2004(05):46-50,57. |
| [38] | Martinez-Juarez A.;Chinarro E.;Recio P.;Pascual C.;Jurado JR.;Sanchez L. .Electrical characterisation of ceramic conductors for fuel cell applications[J].Solid state ionics,2000(1/4):525-528. |
| [39] | Yu H C;Fung K Z;Guo T C et al.Syntheses of perovskite oxides nanoparticles La1-xSrxMO3-δ(M = Co and Cu) as anode electrocatalyst for direct methanol fuel cell[J].Electrochimica Acta,2004,50:811-816. |
| [40] | Raghuveer V.;Xanthopoulos N.;Mathieu HJ.;Viswanathan B.;Thampi KR. .Rare earth cuprates as electrocatalysts for methanol oxidation[J].Solid state ionics,2001(3/4):263-274. |
| [41] | V.Raghuveer;B.Viswanathan .Can La_2-xSr_xCuO_4 be used as anodes for direct methanol fuel cells?[J].Fuel,2002(17):2191-2197. |
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