论述了稀土在各种废水处理过程中发挥的强化催化作用.展望了掺杂稀土化合物能降低TiO2能带宽度,从而可使TiO2光解材料在太阳光下分解水中有机物成为可能,也有望提高TiO2/O3/UV的废水处理能力;最后指出稀土在废水处理中能够发挥超过一般过渡元素的催化作用,关键可能就在于其f轨道在成键过程中所作的贡献.
参考文献
| [1] | 郭茂林,贾志琦,刘翠玲,董建忠,张纯.中国稀土产业现状及战略安全的几点建议[J].科技情报开发与经济,2009(32):95-98. |
| [2] | Deepak B. Akolekar;Suresh K. Bhargava;Irfan Shirgoankar;Jaidev Prasad .Catalytic wet oxidation: an environmental solution for organic pollutant removal from paper and pulp industrial waste liquor[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2002(1/2):255-262. |
| [3] | Laetitia O et al.Catalytic wet air oxidation of phenol and acrylic acid over Ru/C and Ru-CeO2/C catalysts[J].Applied Catalysis B:Environmental,2000,25(10):267-275. |
| [4] | 程鼎,朱世云,王军芳,蔡伟民.催化剂及其制备对催化湿式氧化反应的影响[J].环境科学与技术,2008(01):25-28. |
| [5] | 芮玉兰,韩利华,梁英华.稀土系列催化剂对焦化废水的催化湿式氧化[J].环境科学与技术,2002(03):40-41,48. |
| [6] | 韩利华,李国江,芮玉兰,梁英华.高浓度焦化废水湿式氧化铜系催化剂的研制[J].环境污染治理技术与设备,2003(03):19-22. |
| [7] | 芮玉兰,韩利华,梁英华.稀土系列催化剂对焦化废水的催化湿式氧化[J].环境污染治理技术与设备,2002(02):56-58. |
| [8] | 杨民,王贤高,杜鸿章,孙承林.催化湿式氧化处理农药废水的研究[J].工业水处理,2002(04):35-36. |
| [9] | 付宏祥,蒋展鹏,谭亚军.以乙酸为模型反应物的Ti-Ce复合氧化物湿式氧化催化剂的研制[J].催化学报,2000(04):375-377. |
| [10] | Syed Tajammul Hussain;Abdelhamid Sayari;Faical Larachi .Enhancing the stability of Mn-Ce-O WETOX catalysts using potassium[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2001(1):1-9. |
| [11] | Stanko Hocevar;Ursa Opara Krasovec;Boris Orel;Hasuck Kim;Antonino S.Arico .CWO of phenol on two differently prepared CuO-CeO_2 catalysts[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2000(2):113-125. |
| [12] | 万家峰,冯玉杰,杨少霞,蔡伟民,徐怡珊.CeO2稳定Ru/γ-Al2O3湿空气氧化催化剂的研究[J].分子催化,2002(05):345-348. |
| [13] | Nesheiwat Fares K;Swanson Andy G .Clean contaminated sites using Fenton's reagent[J].Chemical Engineering Progress,2000,96(04):61. |
| [14] | 吴祖成,李伟.UV/H2O2系统光催化氧化降解苯酚废水[J].化工学报,2001(03):277-280. |
| [15] | 刘琼玉,李太友,陈化琼,于丹丹.UV/Fenton氧化-混凝联合工艺处理含酚废水[J].化工环保,2004(04):280-283. |
| [16] | 闻瑞梅;邓守权;梁骏吾 等.一种降解水中有机氯酚的方法[P].中国专利:CN1587091,2005-03-02. |
| [17] | 刘英艳,刘勇弟.碱性条件下日光/FeEDTA/H2O2降解2,4-二氯苯酚的研究[J].环境化学,2006(02):137-140. |
| [18] | Irmak S;Yavuz HI;Erbatur O .Degradation of 4-chloro-2-methylphenol in aqueous solution by electro-Fenton and photoelectro-Fenton processes[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(3/4):243-248. |
| [19] | Dinh-Cuong Vuong;Byron Von Klock .Cyanide and formate destruction with ultraviolet light[P].US:7144514,2006-12-05. |
| [20] | Soerensen Martin;Weckenmann Juergen .Method and device for processing aqueous liquids containing cyanide[P].WO/2000/006498,2000-02-10. |
| [21] | Kopf Patrik .TiO_2 photocatalytic oxidation of monochloroacetic acid and pyridine: influence of ozone[J].Journal of Photochemistry and Photobiology, A. Chemistry,2000(3):163-168. |
| [22] | Iil Akmehmet Balcioglu;Nicola Getoff;Miray Bekblet .A comparative study for the synergistic effect of ozone on the r-irradiated and photocatalytic reaction of 4-chlorobenzaldehyde[J].Journal of Photochemistry and Photobiology A:Chemistry,2000,135(2-3):229-233. |
| [23] | 张彭义,余刚,孙海涛,蒋展鹏.臭氧/活性炭协同降解有机物的初步研究[J].中国环境科学,2000(02):159-162. |
| [24] | 刘德启,魏敏,张颖,周瑾.稀土催化双氧水氧化耦合处理染料中间体废水研究（I）[J].环境污染与防治,2002(03):135-137. |
| [25] | Fujishima A;Honda K .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38. |
| [26] | 魏国,张昱,杨敏,高迎新,张力平.光助非均相Fenton体系用于活性艳红X-3B脱色的研究[J].环境污染治理技术与设备,2005(06):7-11. |
| [27] | Wang J;Park J N;Wei X Y et al.Room-temperature heterogeneous hydroxylation of phenol with hydrogen peroxide over Fe2+,Co2+ ion-exchanged Na beta zeolite[J].Chemical Communications,2003,7(05):628-629. |
| [28] | Zou Lixia,Zhong Qin,Liu Qingcheng.Preparation and Characterization of Microporous Nano-Tungsten Trioxide and Its Photocatalytic Activity after Doping Rare Earth[J].稀土学报（英文版）,2006(01):60-66. |
| [29] | 岳林海 .稀土元素掺杂二氧化钛催化剂光降解久效磷的研究[J].上海环境科学,1998,17(09):17-19. |
| [30] | 孙根行,刘梅.非均相Fenton反应处理污水的研究现状及展望[J].江西师范大学学报（自然科学版）,2008(05):563-567,573. |
| [31] | 郑展望,雷乐成,张珍,岑沛霖.非均相UV/Fe-Cu-Mn-Y/H2O2反应催化降解4BS染料废水[J].环境科学学报,2004(06):1032-1038. |
| [32] | 郑展望,雷乐成,徐生娟,岑沛霖.Heterogeneous UV/Fenton catalytic degradation of wastewater containing phenol with Fe-Cu-Mn-Y catalyst[J].浙江大学学报(英文版),2004(02):206-211. |
| [33] | 李来胜,祝万鹏,张彭义,陈中颖,陈乐.TiO2薄膜光催化臭氧化邻苯二酚[J].催化学报,2003(03):163-168. |
| [34] | 方喜玲;施汉昌 .高级氧化技术处理水中难降解有机物的比较研究[J].给水排水,2005,31(05):114. |
| [35] | Cornish Benjamin J.P.A .Hydrogen peroxide enhanced photocatalytic oxidation of microcystin-LR using titanium dioxide[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2000(1):59-67. |
| [36] | Chen TF.;Lei WG.;Doong RA. .Photocatalytic degradation of parathion in aqueous TiO2 dispersion: The effect of hydrogen peroxide and light intensity[J].Water Science and Technology,1998(8):187-194. |
| [37] | 毛绍春;高文键;李春林 等.UV/Fenton/TiO2 法处理含酚废水的研究[J].云南大学学报,2004,26:154-156. |
| [38] | 杨运平,唐金晶,方芳,郭劲松.UV/TiO2/Fenton光催化氧化垃圾渗滤液的研究[J].中国给水排水,2006(07):34-37,41. |
| [39] | Gubanov V A;Ellis D E;Fetiev A A .Rare-eareh orthovanadates:covalency,chemical bonding,and optical spectra[J].Journal of Solid State Chemistry,1977,21(04):303-324. |
| [40] | 闵新民;沈尔忠;江元生 等.镧系三氟化物的SCF-Xα-SW研究[J].化学学报,1990,48(10):973-976. |
| [41] | 刘文剑,洪功义,黎乐民,徐光宪.EuO的非相对论与相对论非局域密度泛函计算[J].科学通报,1995(19):1771-1773. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%