综述了甲基磺酸铈(Ⅳ)氧化有机化合物及其在有机合成和医药中间体合成中的应用,讨论了它在烷基芳香醛、酮和多环芳香醛、酮和醌合成中是一个高效氧化试剂,产品具有高收率和高选择性.
参考文献
[1] | Kreh R P;Spotnitz R M .Oxidation of organic compounds using ceric ions in aqueous methanesulfonic acid[P].United State Patent:4639298,1987-01-27. |
[2] | Kreh R P;Spotnitz R M .Oxidation of organic compounds[P].European Patent Application:EP0244812Al,1987-11-11. |
[3] | Kreh R P;Spomitz R M;Lundquist J T .Mediated electrochemical synthesis of aromatic aldehydes,ketones,and quinones using ceric methanesulfonate[J].Journal of Organic Chemistry,1989,54(07):1526-1531. |
[4] | Kreh R P;Spotnitz R M .Oxidation of organic compounds using ceric methanesulfonate in an aqueous organic solution[P].United State Patent:4670108,1987-06-02. |
[5] | Devadoss V.;Noel M.;Jayaraman K.;Basha CA. .Electrochemical behaviour of Mn3+/Mn2+, Co3+/Co2+ and Ce4+/Ce4+ redox mediators in methanesulfonic acid[J].Journal of Applied Electrochemistry,2003(3/4):319-323. |
[6] | Robert P K;Jessup Md .Cerium oxidant[P].United State Patent:4794172,1988-12-27. |
[7] | 李彤,郭燕文,张军良,叶彦春.新一代绿色化学--电合成邻硝基苯甲醛[J].化学试剂,2004(04):225-227. |
[8] | Jean J. Lozar;Andre J. Savall .Oxidation of o-Nitrotoluene by Cerium(Ⅳ) Methanesulfonate[J].Industrial & Engineering Chemistry Research,1995(9):3149-3153. |
[9] | Kreh R P;Spotnitz R M;Lundquist J T .Selective oxidations with ceric methanesulfonate and cerium trifluoromethanesulfonate[J].Tetrahedron Letters,1987,28(10):1067-1068. |
[10] | Robin Roussel .Cerium mediated electrosynthesis of panisaldehyde[D].Vancouver Canada:The University of British Columbia,1996. |
[11] | V.Devadoss;C.Ahmed Basha;K.Jayaraman .Indirect Electrochemical Oxidation of p-Methoxy-Toluene to p-Methoxy-Benzaldehyde Using Ceric Methanesulphonate:A Scale-up Study[J].Industrial & Engineering Chemistry Research,2008(14):4607-4616. |
[12] | Vijayabarathi T;Velayutham D;Noel M .Influence of aromatic reactants and products involved in the stage electrochemical oxidation on the voltammetric behaviour of Ce(Ⅳ)/Ce(Ⅲ) redox couple[J].Journal of Applied Electrochemistry,2001,31:979-986. |
[13] | Harrison S .Titanium and cerium containing acidic electrolyte[P].United State Patent:5679235,1997-10-21. |
[14] | Alexander F.Maclean;Adin L .Process for oxidizing olefins to carbonyl compounds[P].United State Patent:3459644,1969-08-05. |
[15] | Kunihiko Mohri;Kimiaki Isobe;Manabu Maeda;Taroh Takeda;Ryoko Ohkubo;Yoshisuke Tsuda .Studies toward Total Synthesis of Non-Aromatic Erythrinan Alkaloids. 7. Synthesis of Cocculolidine Skeleton[J].Chemical and Pharmaceutical Bulletin,1998(12):1872-1877. |
[16] | Harrison S .Indirect cerium mediated electrosynthesis[P].United State Patent:5516407,1996-05-14. |
[17] | Harrison S .Indirect cerium mediated electrosynthesis[P].United State Patent:5296107,1994-03-22. |
[18] | Pichaichanarong P;Spomitz R M;Kreh R P .Simulation of a mediated electrochemical process[J].Chemical Engineering Communications,1990,94(01):119-130. |
[19] | Kreh R P .Oxidation of organic compounds using a catalyzed cerium(Ⅳ) composition[P].United State Patent:4701245,1987-10-20. |
[20] | Harrison S .Indirect cerium mediated electrosynthesis[P].United State Patent:5705049,1998-01-06. |
[21] | Harrison S .Electrosynthesis of aromatic quinones[P].European Patent Application:EP0919533A1,1999-06-02. |
[22] | Spotnitz R M;Kreh R P;Lundquist J T .Mediated electrosynthesis with cerium (Ⅳ) in methanesulphonic acid[J].Journal of Applied Electrochemistry,1990,20:209-215. |
[23] | Davis D D;Sullivan D L .Process for the preparation of dodecanedioic acid[P].United State Patent:5026461,1991-06-25. |
[24] | Edward F;Moran J;Wenonah N .Process for the preparation of 4-phenylquinol[P].United State Patent:4945183,1990-07-31. |
[25] | Aleixo PC.;Romero JR.;Cho LY. .Oxygen as an oxidizing agent in electrocatalytic oxidation of beta-dicarbonylic compounds using Ce-IV as a mediator[J].Journal of Catalysis,2000(1):248-251. |
[26] | Cho L.Y.;Madurro J.M.;Romero J.R. .Electrooxidation of #beta#-Dicarbonyl Compounds Using Ceric Methanesulfonate a sMediator:Some Kinetics and Spectroscopic Studies[J].Journal of Catalysis,1999(1):31-35. |
[27] | Cho L Y;Romero J R .Electrocatalytic oxidation of βdicarbonyl compounds using ceric methanesulphonate as mediator[J].Quimica Nova,1998,21(02):144-145. |
[28] | Lavagnoli L V;Madurro J M;Romero J R .Electrocatalytic oxidation of alcohols and diols in a biphasic medium using C,e (Ⅳ) methanesulfonate as mediator[J].Qu(i)mica Nova,1998,21(06):731-734. |
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