利用溶胶-凝胶法制备系列Gd2-xEuxWO6红色荧光粉,XRD测试表明Gd2-xEuxWO6具有单斜晶系结构;在298 nm或395 nm激发下,荧光粉主要发射出对应于Eu3+5的D0→7 F2能级跃迁的612 nm红光;当Gd2-xEuxWO6中Eu3+的掺杂量为50%时,荧光粉612nm红光强度最强;在合成过程中适当添加聚乙二醇(PEG)和柠檬酸能改善荧光粉的红光发射强度.
参考文献
[1] | Naruke H.;Yamase T. .Structures of novel R2Mo5O18 and R6Mo12O45 (R = Eu and Gd) prepared by thermal decomposition of polyoxomolybdate precursor [R-2(H2O)(12)Mo8O27] center dot nH(2)O[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2002(24):6514-6520. |
[2] | Kodaira CA.;Brito HF.;Felinto MCFC. .Luminescence investigation of Eu3+ ion in the RE2(WO4)(3) matrix (RE = La and Gd) produced using the Pechini method[J].International Journal of Quantum Chemistry,2003(1/2):401-407. |
[3] | Lei F;Yan B;Chen HH .Solid-state synthesis, characterization and luminescent properties of Eu3+-doped gadolinium tungstate and molybdate phosphors: Gd(2-x)MO6:Eu-x(3+) (M = W, MO)[J].International Journal of Quantum Chemistry,2008(10):2845-2851. |
[4] | Klevtsov P V;Kharchenko L Yu;Klcftsova R.F .Crystallization and pdymorphismof rare earch oxymolybdates with the composition Ln2MnO6[J].Soviet Physics Crystallography,1975,20(03):349-353. |
[5] | Brixner L H;Sleight A W;Licis M S .Ln2MoO6-type rare earth molybdates preparation and lattice parameters[J].Journal of Solid State Chemistry,1972,5(02):186-190. |
[6] | TyulinA V;Efremov V A .Polymorphism of oxytungstates TR2WO6:mechanism of structure transformations in erbium oxytungstate (Er2WO6)[J].Kristallografiya,1987,32(02):363-370. |
[7] | Berdonosov PS;Charkin DO;Knight KS;Johnston KE;Goff RJ;Dolgikh VA;Lightfoot P .Phase relations and crystal structures in the systems (Bi,Ln)2WO(6) and (Bi,Ln)(2)MoO6 (Ln = lanthanide)[J].International Journal of Quantum Chemistry,2006(11):3437-3444. |
[8] | Alonso JA;Rivillas F;Martinez-Lope MJ;Pomjakushin V .Preparation and structural study from neutron diffraction data of R2MoO6 (R= Dy, Ho, Er, Tm, Yb, Y)[J].International Journal of Quantum Chemistry,2004(7):2470-2476. |
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