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采用X射线衍射、DTA差热分析和显微金相分析等方法研究了Au-Ag-Gd三元系相图的富Au-Ag区域(Gd≤33.3%;原子数分数,下同),测定了Au-Ag-Gd三元系部分相图的700℃部分等温截面.该截面上有6个单相区:(Ag,Au),Ag51Gd14,Ag2Gd,Au2Gd,Gd14Au51和GdAu6;9个两相区:Ag51 Gd14+(Ag,Au),Ag51 Gd14+Ag2Gd,Ag2Gd+Gd14Au51,(Ag,Au)+Au2Gd,Ag2Gd+Au2Gd,(Ag,Au)+Gd14Au51,Ag51Gd14+Au2Gd,Gd14Au51+GdAu6和(Ag,Au)+GdAu6;4个三相区:(Ag,Au)+Gd14Au51+Au2Gd,Ag51 Gd14+(Ag,Au)+Au2Gd,Ag51Gd14+Ag2Gd+Au2Gd和(Ag,Au)+GdAu6+Gd14Au51.在该成份区域未发现新的三元化合物.

参考文献

[1] Kiessler G;Gebhardt E;Steeb S .The silver - gadolinium system[J].Journal of the Less-Common Metals,1972,26:293-298.
[2] Gschneidner K A Jr;McMasters O D;Alexander D G et al.Factors influencing the formation of silver - rich solid solutions in rare earth - silver alloy systems[J].Metallurgical and Materials Transactions,1970,1:1961-1971.
[3] McMasters O D;Gschneidner K A Jr;Venteicher R F .Grystallography of the silver - rich rare - earth - silver intermetallie compounds[J].Acta Crystallographica,1970,B26:1224-1229.
[4] Bailey D M;Kline G R .The crystal structure of GdAg3.6[J].Acta Crystallographica,1971,B27:650-653.
[5] Gschneidner K A Jr;Calderwood F W .The Ag - Gd(silver - gadolinium) system[J].Bulletin of Alloy Phase Diagrams,1985,6(02):138-140.
[6] Chao C C;Luo H L;Duwez P .CsCl - type compounds in binary alloys of rare - earth metals with gold and silver[J].Journal of Applied Physics,1963,34(07):1971-1973.
[7] Dwight A E;Downey J W;Conner R A Jr .Some C11b- type compounds of Sc, Y and the lanthanides with Cu, Ag and Au[J].Acta Crystallographica,1967,22:745-747.
[8] Sadagopan V;Giessen B C;Grant N J .Crystal chemistry of Au- rich binary alloy phases with the heavy rare earths[J].Journal of the Less-Common Metals,1968,14:279-290.
[9] McMasters O D;Gschneidner K A Jr .Stoichiometry, crystal structures and some melting points of the lanthanide - gold alloy[J].Journal of the Less-Common Metals,1971,25:135-160.
[10] Rider P E;Gschneidner K A Jr;McMasters O D .Gold - rich rare - earth - gold solid solutions[J].Transactions of the Metallurgical Society of AIME,1965,233:1488-1496.
[11] Gsehneidner K A Jr;Calderwood F W.The Au - Gd(gold - gadolinium)system[C].Phase Diagrams of Binary Gold Alloys ASMInternational,1987:118-121.
[12] 何纯孝;马光辰;王文娜.贵金属合金相图[M].北京:冶金工业出版社,1983:3.
[13] SekizawaK;Yasukochi K .[J].Journal of The Physical Society of Japan,1966,21:684-692.
[14] Prince A;Raynor G V;Evans D S.Phase Diagrams of Ternary Gold Alloy[M].London:The Institute of Metals,1990:42.
[15] 徐云,张康侯,李曲波.Ag-Ru-Gd(Gd≤33.3 at%)三元系相图700℃等温截面[J].贵金属,2000(04):1-5.
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