稀燃车用催化剂是汽车尾气净化催化剂今后发展的方向,在稀燃条件下如何处理NOx是稀燃车用催化剂面临的巨大挑战.本文详细地评述了近年来国内外在这方面的研究工作,包括选择催化还原催化剂、存储还原催化剂和组合多功能催化剂的研究进展.
参考文献
| [1] | 周玉明.内燃机废气排放及控制技术[M].北京:人民交通出版社,2001:152-153. |
| [2] | 王建昕;傅立新;黎维彬.汽车排气污染治理及催化转化器[M].北京:化学工业出版社,2000:242-244. |
| [3] | Summers J C;Hegedus L L .Effects of platinum and palladium impregnation on the performance and durability of automobile exhaust oxidizing catalysts[J].Journal of Catalysis,1978,51(01):185-192. |
| [4] | Oh S H;Carpenter J E .Platinum-rhodium synergism in three-way automotive catalysts[J].Journal of Catalysis,1986,98(01):178-190. |
| [5] | Graham G W;Potler T;Baird R J et al.Surface composition of polycrystalline platinum-rhodium following high temperature oxidation in air[J].Journal of Vacuum Science and Technology,1986,A4(03):172-179. |
| [6] | Tadayoshi Hayashi;Shinichi Kikuchi .Exhaust emission control catalyst comprising cerium[P].US 5753580,1998. |
| [7] | Punke A;Dahle U;Tauster S J et al.Trimetallic three way catalysts[R].Society of Automotive Engineers,Technical Paper Series 950255,1995. |
| [8] | Brisley R J;Chandler G R;Jones H R et al.The use of palladium in advance catalysts[R].Society of Automotive Engineers,Technical Paper Series 950259,1995. |
| [9] | 游少雄,冯长根,王丽琼,曾庆轩,安琴,王亚军.双层单钯三效催化剂（TWC）的研究[J].工业催化,2001(05):46-49. |
| [10] | A. Fritz;V. Pitchon .The current state of research on automotive lean NO_x catalysis[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1997(1):1-25. |
| [11] | Armor J N .Catalytic removal of nitrogen oxides:where are the opportunities[J].Catalysis Today,1995,26(02):99-105. |
| [12] | Iwamoto M;Furukawa H;Mine Y.Copper(Ⅱ)ion-exchanged ZSM-5 zeolites as highly active catalysts for direct and continuous decomposition of nitrogen monoxide[J].Journal of the Chemical Society,Chemical Communications,1986:1272-1273. |
| [13] | Yuejin Li;Hall W K .Stoichiometric catalytic decomposition of nitric oxide over Cu/ZSM-5 catalysts[J].Journal of Physical Chemistry,1990,94:6145-6148. |
| [14] | Toshiyuki Tanaka;Koji Yokota;Noritake Isomura et al.Selective reduction of NO over Pt-Mo catalysts under lean static conditions[R].R&D Review of Toyota CRDL:Research Report,1998. |
| [15] | Qi Sun;Zhi-Xian Gao;Hai-Ying Chen;Wolfgang M.H.Sachtler .Reduction of NO_x with Ammonia over Fe/MFI:Reaction mechanism Based on Isotopic Labeling[J].Journal of Catalysis,2001(1):89-99. |
| [16] | Chen Hai-Ying;Voskoboinikov Timur;Sachtler Wofgang M.H. .Reaction Intermediates in the Selective Catalytic Reduction of NO_Xover Fe/ZSM-5[J].Journal of Catalysis,1999(1):91-99. |
| [17] | Hums E .Is advanced SCR technology at a standstill?a provocation for the academic community and catalyst manufacturer[J].Catalysis Today,1998,42(1-2):25-35. |
| [18] | PARVULESCU V I;Grange P;Delmon B .Catalytic removal of NO[J].Catalysis Today,1998,46(04):233-316. |
| [19] | Iwamoto M .Heterogeneous catalysis for removal of NO in excess oxygen progress in 1994[J].Catalysis Today,1996(29):29-35. |
| [20] | Yvonne Traa;Beate Burger;Jens Weitkamp .Zeolite-based materials for the selective catalytic reduction of NO_x with hydrocarbons[J].Microporous and Mesoporous Materials,1999(1):3-41. |
| [21] | Iwamoto M.Proc.Catal.Tech.for Removal of Nitrogen Monoxide[M].Catal.Soc.Tokyo.Jan,1990:17-22. |
| [22] | Held W;Konig A;Richter T et al.Catalytic NoDx reduction in net oxidizing exhaust gas[R].Society of Automotive Engineers,Technical Paper Series 900496,1990. |
| [23] | Hai-Ying Chen;Timur Voskoboinikov;Wolfgang M H Sachtler .Reduction of NOx over catalysts:mechanistic causes of activity differences between alkanes[J].Catalysis Today,1999,54(04):483-494. |
| [24] | Kintachi Y;Hamada H;Tabata M et al.Selective reduction of NO with propene over In2O3-Al2O3[J].Catalysis Letters,1990,6(02):239-245. |
| [25] | Zuzaniuk V;Meunier F C;Ross J R H.Possible intermediates in the selective catalytic reduction of NOx:differences in the reactivity of nitro-compounds and tert-butyl nitrite over g-A1203[J].Chemical Communications,1999:815-816. |
| [26] | Hanada H;Kintashi Y;Inaba M et al.Role of supported metals in the selective reduction of nitrogen monoxide with hydrocarbons over metal/alumina catalysts[J].Catalysis Today,1996(29):53-57. |
| [27] | Xiankuan Zhang;Walters A B;Vannice M A .NOx decomposition and reduction by methane over La2O3[J].Applied Catalysis B:Environmental,1994,4(04):237-256. |
| [28] | HamadaH;Kintashi Y;Sasaki M et al.Transition metal-promoted silica and alumina catalysts for the selective reduction of nitrogen monoxide with propane[J].Applied Catalysis,1991,75:L1-L8. |
| [29] | Yan JY.;Sachtler WMH.;Kung HH.;Kung MC. .CO/AL2O3 LEAN NOX REDUCTION CATALYST[J].Journal of Catalysis,1997(1):178-186. |
| [30] | Torikai Y;Yahiro H;Mizuno N et al.Enhancement of catalytic activity of alumina by copper addition for selective reduction of nitrogen monoxide by ethene in oxidizing atmosphere[J].Catalysis Letters,1991,9:91-96. |
| [31] | F. C. Meunier;J. P. Breen;V. Zuzaniuk;M. Olsson;J. R. H. Ross .Mechanistic Aspects of the Selective Reduction of No by Propene Over Alumina and Silver-Alumina Catalysts[J].Journal of Catalysis,1999(2):493-505. |
| [32] | Deborah L. Mowery;Michael S. Graboski;Robert L. McCormick;Tim R. Ohno .Deactivation of PdO-Al_2O_3 oxidation catalyst in lean-burn natural gas engine exhaust: aged catalyst characterization and studies of poisoning by H_2O and SO_2[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1999(3):157-169. |
| [33] | F. Jayat;C. Lembacher;U. Schubert;J.A. Martens .Catalytic NO_x reduction in lean burn exhaust over Pt/silica catalysts with controlled Pt particle size[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1999(3):221-226. |
| [34] | Till Gerlach;Frank-Walter Schutze;Manfred Baerns .An FTIR Study on the Mechanism of the Reaction between Nitrogen Dioxide and Propene over Acidic Mordenites[J].Journal of Catalysis,1999(1):131-137. |
| [35] | Maria Cristina Campa;Sergio De Rossi;Giovanni Ferraris;Valerio Indovina .Catalytic activity of Co-ZSM-5 for the abatement of NOx with methane in the presence of oxygen[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1996(3):315-331. |
| [36] | HamadaH;Kintaishi Y;Sasaki M et al.Selective reduction of nitrogen monoxide with propane over alumina and H/ZSM-5 zeolite[J].Applied Catalysis,1991,70:L15-L20. |
| [37] | EI M;EI Malki;R A Van Santen.Isothermal oscillations of N2O decomposition over Fe/ZSM-5 catalysts;effect of H2O vapor[J].Microporous and Mesoporous Materials,2000:235-244. |
| [38] | Li Y;Armor J N .Catalytic reduction of nitrogen oxides with methane in the presence of excess oxygen[J].Applied Catalysis B:Environmental,1992,1(04):L31-L40. |
| [39] | Li Y;Armor J N .Selective catalytic reduction of NOx with methane over metal exchange zeolites[J].Applied Catalysis B:Environmental,1993,2(02):239-256. |
| [40] | Yogo K;Ihara M;Terasaki I .Selective catalytic reduction of nitric oxide by ethane on gallium ion-exchanged ZSM-5 under oxygen-rich conditions[J].Applied Catalysis B:Environmental,1993,2(01):L1-L11. |
| [41] | Ohtsuka H;Tabata T;Okada O et al.A study on the roles of cobalt species in NOx reduction propane on Co-Beta[J].Catalysis Today,1998,42(1-2):45-50. |
| [42] | Aylor A W;Lobree L J;Reimer J A.An infrared study of NO reduction by CH4 over Co-ZSM-5[A].,1996:661-670. |
| [43] | Adelman BJ.;Lei GD.;Sachtler WMH.;Beutel T. .MECHANISTIC CAUSE OF HYDROCARBON SPECIFICITY OVER CU/ZSM-5 AND CO/ZSM-5 CATALYSTS IN THE SELECTIVE CATALYTIC REDUCTION OF NOX[J].Journal of Catalysis,1996(1):327-335. |
| [44] | EI M;EI Malki;R A Van Santen et al.Introduction of Zn,Ga and Fe into H/ZSM-5 cavities by sublimation;identification of catalytic sites[J].Journal of Physical Chemistry B,1999,103:4611-4622. |
| [45] | Timur Voskoboinikov;Hai-Ying Chen;Wolfgang M H Sachtler .Characterization of Fe/ZSM-5 by isotopic exchange with O2[J].Journal of Molecular Catalysis A:Chemical,2000,155:155-1680. |
| [46] | Wen B;Qi Sun;Wolfgang M .H/D exchange of methane over transition metal/MEI catalysts[J].Applied Catalysis A:General,2002,229:11-22. |
| [47] | Feng XB.;Hall WK. .FEZSM-5 - A DURABLE SCR CATALYST FOR NOX REMOVAL FROM COMBUSTION STREAMS[J].Journal of Catalysis,1997(2):368-376. |
| [48] | Aylor AW.;Reimer JA.;Bell AT.;Lobree LJ. .NO ADSORPTION, DESORPTION, AND REDUCTION BY CH4 OVER MN-ZSM-5[J].Journal of Catalysis,1997(2):390-401. |
| [49] | Ana Bahamonde;Carlos Knapp;Pedro Avila et al.Titania based platinum monolithic catalysts for lean-bum De NOx process[J].Applied Catalysis B:Environmental,1998,19(01):1-7. |
| [50] | Wen B;Qi Sun;Wolfgang M H Sachtler .Function of Pdon clusters,Pd2+(oxo-)ions and PdO clusters in the catalytic reduction of NO with methane over Pd/MFI catalysts[J].Journal of Catalysis,2001,204(02):314-323. |
| [51] | Wen B;Wolfgang M;H Sachtler .Synergism of cobalt and palladium in MFI zeolites of relevance to NOx reduction with methane[J].Chemical Physics and Physical Chemistry,2002,4:1983-1989. |
| [52] | Karl C C Kharas;Heinz J Robota .Reduction of NOx in the exhaust from lean-burn combustion engines[P].US:6365118B1,2002. |
| [53] | Pitchon V.;Fritz A. .The Relation between Surface State and Reactivity in the DeNO X Mechanism on Platinum-Based Catalysts[J].Journal of Catalysis,1999(1):64-74. |
| [54] | Christian Rottlander;Renato Andorf;Carsten Plog;Bernd Krutzsch;Manfred Baerns .Selective NO reduction by propane and propene over a Pt/ZSM-5 catalyst: a transient study of the reaction mechanism[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1996(1):49-63. |
| [55] | Orietta Monticelli;Raf Loenders;Pierre A. Jacobs;Johan A. Martens .NO_x removal from exhaust gas from lean burn internal combustion engines through adsorption on FAU type zeolites cation exchanged with alkli metals and alkaline earth metals[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1999(3):215-220. |
| [56] | Yuejin Li Edison .SOx tolerant NOx trap catalysts and methods of making and using the same[P].US:6419890B1,2002. |
| [57] | Yan JY.;Sachtler WMH.;Kung MC.;Kung HH. .Synergistic effect in lean NOx reduction by CH4 over Co/Al2O3 and H-zeolite catalysts[J].Journal of Catalysis,1998(2):294-301. |
| [58] | Konno M;Chikahisa T;Tadashi M et al.Catalytic reduction of NoDx in actual diesel engine exhaust[R].Society of Automotive Engineers,Technical Paper Series 920091,1992. |
| [59] | Monroe D R;DiMaggio C L;Beck D D et al.Evaluation of a Cu/zeolite catalyst to remove NoDx from lean exhaust[R].Society of Automotive Engineers,Technical Paper Series 930737,1993. |
| [60] | T. Tanabe;T. Iijima;A. Koiwai;J. Mizuno;K. Yokota;A. Isogai .ESR study of the deactivation of Cu-ZSM-5 in a net oxidizing atmosphere[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1995(2):145-153. |
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