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金因其良好的物理化学性质和催化活性在低温燃料电池技术中具有很好的应用前景.本文就金在此方向的研究进展进行综述,包括:金催化剂选择氧化燃料电池氢燃料中的CO以及Pt-Au系电催化剂、Pd-Au系电催化剂、以金为主体的电催化剂的研究状况.同时简要介绍了低温燃料电池电催化剂的发展现状和金应用于电催化剂的基础.

参考文献

[1] William Hernando Lizcano-Valbuena;Dayse Caldas de Azevedo;Ernesto Rafael Gonzalez .Supported metal nanoparticles as electrocatalysts for low-temperature fuel cells[J].Electrochimica Acta,2004(8):1289-1295.
[2] 詹姆斯·拉米尼;安德鲁·迪克斯.燃料电池系统-原理·设计·应用[M].北京:科学出版社,2006
[3] 索春光,赵晓光,张鹏,刘晓为,张宇峰.直接甲醇燃料电池阳极抗CO催化剂的研究进展[J].贵金属,2008(03):66-70.
[4] 钟文健,董新法,陈胜洲,林维明.一种新型非贵金属氧还原电催化剂[J].电池,2003(04):245-248.
[5] 胡西多,曾志峰,徐常威,于非,谢晖.碱性甲醇燃料电池阳极催化剂的研究进展[J].东莞理工学院学报,2007(01):30-35.
[6] 刘春涛,史鹏飞,张新荣.甲醇重整气中CO去除的研究进展[J].电池,2003(05):316-318.
[7] Haruta M;Tsubota S;Kobayashi T et al.Low-temperature oxidation of CO over gold supported on TiO2,α-Fe2O3,and Co3O4[J].Journal of Catalysis,1993,144:175-192.
[8] Rosa M;Sanchez T;Atsushi U .Selective oxidation of CO in hydrogen over gold supported on manganese oxides[J].Journal of Catalysis,1997,168:125-127.
[9] Cecile Rossignol;Sandrine Arrii;Franck Morfin;Laurent Piccolo;Valerie Caps;Jean-Luc Rousset .Selective oxidation of CO over model gold-based catalysts in the presence of H_2[J].Journal of Catalysis,2005(2):476-483.
[10] Bethke GK.;Kung HH. .Selective CO oxidation in a hydrogen-rich stream over Au/gamma-Al2O3 catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2000(Special Issue SI):43-53.
[11] 王东辉;程代云;郝郑平.纳米金催化剂及其应用[M].北京:国防工业出版社,2006
[12] 张金昌,王艳辉,马润宇,吴迪镛,王祥生.氧化锌负载金和铂选择催化氧化燃料电池氢源中微量CO的研究[J].北京化工大学学报(自然科学版),2003(01):1-4.
[13] 黄德彬.有色金属材料手册[M].北京:化学工业出版社,2005:62.
[14] Cameron D;Holliday R;Thompson D .Gold future role in fuel cell systems[J].Journal of Power Sources,2003,118:298-303.
[15] 董守安.纳米技术中的金元素[J].贵金属,2003(01):54-61.
[16] Tang H;Chen JH;Wang MY;Nie LH;Kuang YF;Yao SZ .Controlled synthesis of platinum catalysts on Au nanoparticles and their electrocatalytic property for methanol oxidation[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2004(1/2):43-48.
[17] Shaojun Guo;Youxing Fang;Shaojun Dong .High-Efficiency and Low-Cost Hybrid Nanomaterial as Enhancing Electrocatalyst:Spongelike Au/Pt Core/Shell Nanomaterial with Hollow Cavity[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(45):17104-17109.
[18] Biswas PC.;Enyo M.;Haruta M.;Nodasaka Y. .ELECTRO-OXIDATION OF CO AND METHANOL ON GRAPHITE-BASED PLATINUM ELECTRODES COMBINED WITH OXIDE-SUPPORTED ULTRAFINE GOLD PARTICLES[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1995(1/2):167-177.
[19] Luo J;Njoki PN;Lin Y;Mott D;Wang LY;Zhong CJ .Characterization of carbon-supported AuPt nanoparticles for electrocatalytic methanol oxidation reaction[J].Langmuir: The ACS Journal of Surfaces and Colloids,2006(6):2892-2898.
[20] Luo J;Njoki PN;Lin Y;Wang LY;Zhong CJ .Activity-composition correlation of AuPt alloy nanoparticle catalysts in electrocatalytic reduction of oxygen[J].Electrochemistry communications,2006(4):581-587.
[21] Li Ma;Huamin Zhang;Yongmin Liang .A novel carbon supported PtAuFe as CO-tolerant anode catalyst for proton exchange membrane fuel cells[J].Catalysis Communications,2007(6):921-925.
[22] Zeng J H;Yang J;Lee J Y et al.Preparation of carbon-supported core-shell Au-Pt nanoparticles for methanol oxidation reaction:the promotional effect of the Au core[J].Journal of Physical Chemistry B,2006,110:24606-24611.
[23] Santhosh P;Gopalan A;Lee KP .Gold nanoparticles dispersed polyaniline grafted multiwall carbon nanotubes as newer electrocatalysts: Preparation and performances for methanol oxidation[J].Journal of Catalysis,2006(1):177-185.
[24] 黄明华,孙旭平,毕立华,申燕,刘柏峰,董绍俊.金纳米粒子和杂多酸的多层组装及其对氧的催化还原[J].复旦学报(自然科学版),2004(04):482-486.
[25] El-Deab M S;Ohsaka T .Electrocatalysis by design:effect of the loading level of Au nanoparticles-MnOx nanoparticles binary catalysts on the electrochemical reduction of molecular oxygen[J].Electrochimica Acta,2007,52:2166–2174.
[26] T.J.Schmidt;Z.Jusys;H.A.Gasteiger;R.J.Behm;U.Endruschat;H.Boennemann .On the CO tolerance of novel colloidal PdAu/carbon electrocatalysts[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2001(1/2):132-140.
[27] Nie M;Tang HL;Wei ZD;Jiang SP;Shen PK .Highly efficient AuPd-WC/C electrocatalyst for ethanol oxidation[J].Electrochemistry communications,2007(9):2375-2379.
[28] Nie M;Shen P K;Wei Z D .Nanocrystaline tungsten carbide supported Au-Pd electrocatalyst for oxygen reduction[J].Journal of Power Sources,2007,167:69-73.
[29] Zhou WJ;Lee JY .Highly active core-shell Au@Pd catalyst for formic acid electrooxidation[J].Electrochemistry communications,2007(7):1725-1729.
[30] 陈酉贵,庄林,陆君涛.碱性直接醇燃料电池非铂阳极催化剂[J].催化学报,2007(10):870-874.
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