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  4. RuH2 (PPh3)4 在催化有机反应中的应用

贵金属, 2009, 30(3): 54-61. doi: 10.3969/j.issn.1004-0676.2009.03.013

RuH2 (PPh3)4 在催化有机反应中的应用

乐传俊 1, , 顾黎萍 2, , 何仁 3,

1.常州工学院,理学院化学系,江苏,常州,213002;大连理工大学,精细化工国家重点实验室,辽宁,大连,116012

2.常州工学院,理学院化学系,江苏,常州,213002

3.大连理工大学,精细化工国家重点实验室,辽宁,大连,116012

关键词： 催化化学 , RuH2(PPh3)4 , 催化反应 , "一石多能"方法 , 绿色化

RuH2(PPh3)4 as a Catalyst for Organic Reactions

介绍了RuH2(PPh3)4 (1)在催化有机反应中的应用进展 .含有Ru-H键的结构简单配合物1能催化氢转移反应(异构化、氧化反应和还原反应)、碳碳键形成反应和氰基三键的亲核加成反应;其催化的反应具有条件温和、效率高和环境友好的特点,因而具有潜在的工业应用价值和"一石多能"的催化方法论意义.

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