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用静态法较系统地研究了新型硫脲树脂从酸性含金氯化溶液中吸附金及其解吸金的性能,结果表明,在实验条件下,新树脂在含有Au~(3+)、Cu~(2+)、 Ni~(2+) 和 Fe~(3+)等离子的混合体系中,对Au~(3+)有良好的吸附容量和选择性,并能定量地解吸树脂所吸附的Au~(3+).在适宜条件下,该树脂对金的吸附率和解吸率均达到98%以上.

In this paper, the adsorption property of a new thiourea chelating resin for gold from gold-bearing chloride solution and its desorption were studied. In the coexisting system of Au~(3+), Cu~(2+), Ni~(2+) and Fe~(3+), the resin had excellent absorption capacity and selectivity for Au~(3+), and the adsorbed Au~(3+) could be desorbed quantitatively. The both adsorptive and desorbing percentages can reach 98% under the proper conditions.

参考文献

[1] 周小华,董学畅,吴立生,杨金美,赵雷修.新型硫脲螯合树脂的合成及对钯(Ⅱ)吸附性能的研究[J].贵金属,2007(04):41-44.
[2] 株洲冶炼厂.有色冶金中元素的分离与测定[M].北京:冶金工业出版社,1979
[3] 杨元法;陈义镛 .4-氨基-1,2,3-三氮唑树脂对Ir(Ⅳ)和Ru(Ⅳ)的吸附行为[J].离子交换与吸附,1996,12(02):136-142.
[4] 北川浩;铃木谦一朗.吸附的基础与设计[M].北京:化学工业出版社,1983
[5] Boyd G E;Adamson A W;Myers L S .The exchang adorption of ions from aqueous solutions by organic zeolites Ⅱ kinetics[J].Journal of the American Chemical Society,1947,69:2836.
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