简述了国内外贵金属分析常用的分离富集方法,包括火试金法、共沉淀法、萃取法、离子交换法、吸附法、液膜法等,并从多种分离富集方法联用的角度,介绍了2种分离贵金属元素的新方法:离子交换法与活性炭吸附的联用技术以及火试金法与Te沉淀的联用技术.最后对未来发展的趋势进行了展望.
参考文献
| [1] | 吴晓峰,汪云华,范兴祥,赵家春,关晓伟,顾华祥.贵金属提取冶金技术现状及发展趋势[J].贵金属,2007(04):63-68. |
| [2] | 刘亮,柯玲.铅试金法测定铅精矿及粗铅中的金、银[J].分析试验室,2007(z1):111-115. |
| [3] | Shirai N.;Nishino T.;Li XL.;Amakawa H.;Ebihara M. .Precise determination of PGE in a GSJ reference sample JP-1 by ID-ICPMS after nickel sulfide fire assay preconcentration[J].Geochemical Journal,2003(4):531-536. |
| [4] | 林玉南;胡金星;沈振兴 .锑试金富集痕量金的研究-地质样品中ng/g级金的测定[J].分析化学,1988,16(01):1-4. |
| [5] | Juvonen MR;Bartha A;Lakomaa TM;Soikkeli LA;Bertalan E;Kallio EI;Ballok M .Comparison of recoveries by lead fire assay and nickel sulfide fire assay in the determination of gold, platinum, palladium and rhenium in sulfide ore samples[J].Geostandards and geoanalytical research,2004(1):123-130. |
| [6] | 李晓林,M. Ebihara.铂族元素中子活化分析的微型镍锍试金预富集方法研究[J].岩矿测试,2005(03):167-170. |
| [7] | 李刚,周长祥,袁家义,徐卫东,李俊杰,崔乐金.镍锍试金富集-中子活化分析测定地质样品中的铂族元素[J].河南化工,2003(09):33-36. |
| [8] | Gomez MB.;Gomez MM.;Palacios MA. .ICP-MS determination of Pt, Pd and Rh in airborne and road dust after tellurium coprecipitation[J].Journal of Analytical Atomic Spectrometry,2003(1):80-83. |
| [9] | 施意华,熊传信,黄俭惠.共沉淀富集分离-ICP-MS法测定地球化学勘探样品中的超痕量金、铂、钯[J].黄金,2009(02):43-45. |
| [10] | Soylak M;Tuzen M .Coprecipitation of gold(III),palladium(II) and lead(II) for their flame atomic absorptionspectrometric determinations[J].Journal of Hazardous Materials,2008,152(02):656–661. |
| [11] | Alam M S;Inoue K .Extraction of rhodium from other platinum group metals with Kelex 100 from chloride media containing tin[J].HYDROMETALLURGY,1997,46(03):373-382. |
| [12] | Y.F.Shen;W.Y.Xue .Recovery palladium,gold and platinum from hydrochloric acid solution using 2-hydroxy-4-sec-octanoyl diphenyl-ketoxime[J].Separation and Purification Technology,2007(3):278-283. |
| [13] | 王克太,张彪,柴凤英,陈兴国,胡之德.聚乙二醇-硫酸铵-二溴羧基偶氮氯膦体系萃取分光光度法测定微量钯[J].岩矿测试,2006(01):39-41. |
| [14] | 高云涛,王伟.钯（Ⅱ）碘络合物在丙醇-硫酸铵双水相萃取体系中的分配行为及在钯测定中的应用[J].贵金属,2006(03):45-49,53. |
| [15] | Colin F. Poole .New trends in solid-phase extraction[J].TrAC: Trends in Analytical Chemistry,2003(6):362-373. |
| [16] | 黄章杰,黄锋,谢琦莹.钯与对若丹宁偶氮苯甲酸络合物的固相萃取和光度测定[J].分析试验室,2007(11):38-41. |
| [17] | 余晓雪,孙小梅,葛淑萍,李步海.钯（Ⅱ）与铬（Ⅵ）、锌（Ⅱ）、镉（Ⅱ）的钙黄绿素液固萃取分离及钯的荧光猝灭法测定[J].冶金分析,2008(11):36-39. |
| [18] | Shino Iwao;Samir Abd El-Fatah;Kiyonori Furukawa .Recovery of palladium from spent catalyst with supercritical CO2 and chelating agent[J].The Journal of Supercritical Fluids,2007(2):200-204. |
| [19] | Zbigniew Hubicki;Monika Leszczynska;Bozena Lodyga .Recovery of palladium(II) from chloride and chloride-nitrate solutions using ion-exchange resins with S-donor atoms[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2007(1/3):80-86. |
| [20] | K. Shams;F.Goodarzi .Improved and selective platinum recovery from spent α-alumina supported catalysts using pretreated anionic ion exchange resin[J].Journal of hazardous materials,2006(1/3):229-237. |
| [21] | 徐羽梧;张超灿;董世华 .螯合树脂研究VII:含聚硫醚主链的多乙烯多胺型鳌合树脂的合成及其吸附性能[J].应用化学,1998,5(02):74-76. |
| [22] | 刘芳,董世华.聚硫醚主链的咪唑型螯合树脂合成及吸附性能[J].华南理工大学学报（自然科学版）,1996(07):66. |
| [23] | 董世华;宗振刚;胡运华 等.冠醚聚合物研究V--聚苯乙烯支载的开链硫杂冠醚的合成及其络合性能[J].武汉大学学报(自然科学版),1998,44(04):425-429. |
| [24] | 李现红,佘振宝,闫庆秀,张凯.PAN-S螯合形成树脂分离富集极谱连测地质样品中贵金属[J].世界地质,2007(03):385-389. |
| [25] | 鲍长利,徐昕,宋海欧,张建会,李俊锋.铬变酸-2R负载树脂分离富集微量金和钯[J].吉林大学学报（理学版）,2008(01):131-134. |
| [26] | Matsubara I;Takeda Y .Improved recovery of trace amounts of gold (III),palladium (II) and platinum(IV) from large amounts of cassociated base metals using anion-exchange resins[J].Fresenius'Journal of Analytical Chemistry,2000,366(03):213-217. |
| [27] | Ahmed M. Donia;Asem A. Atia;Khalid Z. Elwakeel .Recovery of gold(III) and silver(I) on a chemically modified chitosan with magnetic properties[J].Hydrometallurgy,2007(3/4):197-206. |
| [28] | Zhang XY;Ding SM;Wang YT;Feng XH;Peng Q;Ma SH .Synthesis and adsorption properties of metal ions of novel azacrown ether crosslinked chitosan[J].Journal of Applied Polymer Science,2006(4):2705-2709. |
| [29] | Shimin Ding;Xueyong Zhang;Xianghua Feng;Yuting Wang;Shulan Ma;Qi Peng;Weian Zhang .Synthesis of N,N'-diallyl dibenzo 18-crown-6 crown ether crosslinked chitosan and their adsorption properties for metal ions[J].Reactive & functional polymers,2006(3):357-363. |
| [30] | 高登征,刘丽华.硅胶固定相的合成改性研究[J].有色矿冶,2005(z1):157,159. |
| [31] | 朱冬冬,胡玉才,于会弟,杨迎霞,刘娴慧.活性炭纤维对贵金属离子吸附性能的研究[J].当代化工,2008(02):136-138. |
| [32] | Suhas;Carrott PJM;Carrott MMLR .Lignin - from natural adsorbent to activated carbon: A review[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2007(12):2301-2312. |
| [33] | Durga Parajuli;Chaitanya R. Adhikari;Hidetaka Kawakita;Kumiko Kajiyama;Keisuke Ohto;Katsutoshi Inoue .Reduction and accumulation of Au(III) by grape waste: A kinetic approach[J].Reactive & functional polymers,2008(8):1194-1199. |
| [34] | Parajuli D;Adhikari CR;Kawakita H;Yamada S;Ohto K;Inoue K .Chestnut pellicle for the recovery of gold[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2009(2):1000-1002. |
| [35] | Beata Godlewska-Zylkiewicz .Biosorption of platinum and palladium for their separation/preconcentration prior to graphite furnace atomic absorption spectrometric determination[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2003(8):1531-1540. |
| [36] | Creamer NJ;Baxter-Plant VS;Henderson J;Potter M;Macaskie LE .Palladium and gold removal and recovery from precious metal solutions and electronic scrap leachates by Desulfovibrio desulfuricans[J].Biotechnology Letters,2006(18):1475-1484. |
| [37] | Bhandare AA.;Argekar AP. .Separation and recovery of platinum and rhodium by supported liquid membranes using bis(2-ethylhexyl)phosphoric acid (HDEHP) as a mobile carrier[J].Journal of Membrane Science,2002(1/2):233-237. |
| [38] | All Kargari;Tahereh Kaghazchi;Mansoureh Soleimani .Extraction of Gold(III)Ions from Aqueous Solutions Using Polyamine Type Surfactant Liquid Membrane[J].The Canadian Journal of Chemical Engineering,2004(6):1301-1306. |
| [39] | Uheida A;Zhang Y;Muhammed M .Transport of palladium(II) through hollow fiber supported liquid membrane facilitated by nonylthiourea[J].Journal of Membrane Science,2004(2):289-295. |
| [40] | Su XG.;Zhang YH.;Zhang JH.;Zhang HQ.;Jin QH.;Wang MJ. .Graphite furnace atomic absorption spectrometric determination of some noble metals using flow injection on-line clean-up[J].Journal of Analytical Atomic Spectrometry,2001(11):1341-1343. |
| [41] | Campbell AJ.;Humayun M. .Trace element microanalysis in iron meteorites by laser ablation ICPMS[J].Analytical chemistry,1999(5):939-946. |
| [42] | 李展强,张汉萍,张学华,李其英,李锡坤.阴离子树脂-活性炭分离富集等离子体发射光谱法测定富钴锰结壳中的痕量金银铂钯[J].岩矿测试,2005(02):141-144. |
| [43] | 郑浩,李红,曾扬,马龙.阴离子交换树脂-活性炭动态吸附无火焰原子吸收法测定矿石中的微量金铂钯[J].岩矿测试,2005(04):299-302. |
| [44] | Gros M.;Lorand JP.;Luguet A. .Analysis of platinum group elements and gold in geological materials using NiS fire assay and Te coprecipitation; the NiS dissolution step revisited[J].Chemical geology,2002(3-4):179-190. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%