针对熔体快淬法制备的非晶Mg65Ni27La8合金利用置换沉积的方法在非晶合金表面沉积金属Ag,以期改善合金电极的循环性能.修饰后的合金电极最大放电比容量虽然略低于修饰前的合金电极(590 mAh/g),但是都显示了较好循环稳定性.当Ag/Mg的摩尔比为1/5时,合金电极最大放电容量为551 mAh/g,且合金经过20个充放电循环后放电比容量保持率仍达69%;线性极化曲线显示其交换电流密度为353 mA/g;表面修饰后的合金颗粒之间的接触阻抗和合金表面的电荷传输阻抗均有不同程度的降低,分别由修饰前的0.91 Ω和3.15 Ω降低到0.33 Ω和0.85 Ω.
参考文献
[1] | 谢昭明,张胜涛,潘复生.镁基储氢复合材料的研究进展[J].功能材料,2003(04):357-360. |
[2] | Y. Wang;X. P. Gao;Z. W. Lu;W. K. Hu;Z. Zhou;J. Q. Qu;P. W. Shen .Effects of metal oxides on electrochemical hydrogen storage of nanocrystalline LaMg{sub}12-Ni composites[J].Electrochimica Acta,2005(11):2187-2191. |
[3] | R. A. H. Niessen;P. Vermeulen;P. H. L. Notten .The electrochemistry of Pd-coated Mg{sub}ySc{sub}(1-y)) thin film electrodes: A thermodynamic and kinetic study[J].Electrochimica Acta,2006(12):2427-2436. |
[4] | 廖彬,吕曼祺,周德惠,范瑛,杨勋,刘晓艰,谭云.镀覆处理对LaNiAl合金贮氢性能影响*[J].功能材料,2001(02):167-168,174. |
[5] | Z.P. Guo;Z.G. Huang;K. Konstantinov;H.K. Liu;S.X. Dou .Electrochemical hydrogen storage properties of nonstoichiometric amorphous MgNi_(1+x)-carbon composites (x = 0.05-0.3)[J].International journal of hydrogen energy,2006(14):2032-2039. |
[6] | Mustafa Anik .Improvement of the electrochemical hydrogen storage performance of Mg_2Ni by the partial replacements of Mg by Al, Ti and Zr[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):109-114. |
[7] | Mao-Sung Wu;Hong-Rong Wu;Yung-Yun Wang;Chi-Chao Wan .Electrochemical investigation of hydrogen-storage alloy electrode with duplex surface modification[J].International journal of hydrogen energy,2004(12):1263-1269. |
[8] | Hydrogen dissociation and diffusion on transition metal (= Ti, Zr, V, Fe, Ru, Co, Rh, Ni, Pd, Cu, Ag)-doped Mg(0001) surfaces[J].International journal of hydrogen energy,2009(4):1922-1930. |
[9] | Qian Li;Kuo-Chih Chou;Qin Lin;Li-Jun Jiang;Feng Zhan .Hydrogen absorption and desorption kinetics of Ag-Mg-Ni alloys[J].International journal of hydrogen energy,2004(8):843-849. |
[10] | Li Qian;Lin Qin;Jiang Lijun .Properties of hydrogen storage alloy Mg_(2-x)Ag_xNi (x=0.05, 0.1, 0.5) by hydriding combustion synthesis[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(1/2):128-132. |
[11] | Notten P H L;Hokkeling P .Double-phase hydride forming compounds-a new class of highly electrocatalytic materials[J].Journal of the Electrochemical Society,1991,138(07):1877-1885. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%