用电沉积法制备铜/镍-钨-磷阴极材料.研究了镀液成分及工艺条件对镀层成分的影响.测量了铜/镍-钨-磷镀层的电催化析氢性能以及在硫酸/硫酸锰溶液中的稳定性.模拟二氧化锰电解生产的条件,测定了该阴极材料的槽电压,并与石墨和铜进行了比较.结果表明,铜/镍-钨-磷是电解生产二氧化锰的优良的阴极材料.
参考文献
| [1] | Green J A S;Lewis F A .[J].Transactions of the Faraday Society,1964,60:2234. |
| [2] | Green J A S;Lewis F A .[J].Transactions of the Faraday Society,1966,62:503. |
| [3] | Green J A S;Lewis F A J .[J].Journal of the Electrochemical Society,1966,113:95. |
| [4] | Withersoon M C;Johnston R C;Lewis F A .[J].Electrochimica Acta,1975,20:519-521. |
| [5] | Conway B E;Harington D A .[J].Electrochimica Acta,1987,32(12):1713-1731. |
| [6] | Brannan J R;Malkin I;Brown C M .Method of in situ plating of an active coating on cathodes of alkali halide electrolysis cells[P].US 4104133,1978. |
| [7] | Gray T J;Guilford C T .Raney alloy coated cathode for chlor-alkali cells[P].US 4240895,1980. |
| [8] | Lohrberg K;Wullenweber H;Muller J et al.process of manufacturing sheet metal elements or strip having a catalytie surface structure[P].US:4278568,1981. |
| [9] | Lohrberg K;Kohkl P .[J].Electrochimica Acta,1984,29(11):1557-1561. |
| [10] | Endon E;Osouma H;DA Y .[J].International Journal of Hydrogen Energy,1987,12(07):473-479. |
| [11] | Mari C M;Fior G .[J].International Journal of Hydrogen Energy,1987,12(03):159-164. |
| [12] | Brawn D E .[J].Electrochimica Acta,1984,29:1551-1556. |
| [13] | Belanger A;Vijh A K .[J].International Journal of Hydrogen Energy,1987,12(04):227-233. |
| [14] | Vermerircnph;Leysenand R;Vandenborre H .[J].Electrochimica Acta,1985,30:1253-1255. |
| [15] | 卢燕平;川岛朝日;桥本功二 .[J].材料保护,1984,5:5-7. |
| [16] | 林修文;郑云;薛文华 等.Ni-W合金电沉积及共析氢电催化性能的研究[J].福建师范大学学报(自然科学版),1995,11(01):60-65. |
| [17] | 郑华均 .电镀非晶态合金控制方法的研究[J].电镀与环保,1996,16(03):3-6. |
| [18] | 谢原寿;蒋文斌 等.NaCl电解槽新阴极材料研究[J].湘潭大学自然科学学报,1997,19(02) |
| [19] | 谢原寿.水溶液电解新阴极材料Ni-Co-S-Mo合金的研究[J].电化学,1998(04):434. |
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