兵器材料科学与工程 , 2004, 27(6): 38-42. doi: 10.3969/j.issn.1004-244X.2004.06.011
7A52铝合金搅拌摩擦焊接头特征分析
张平 1, , 王卫欣 2, , 镍锰合金沉积的电极过程,采用线性扫描伏安法、单电位阶跃计时电流法和交流阻抗谱技术对镍锰合金的电沉积与镍的电沉积进行了对比性研究.结果表明:氯化锰的加入增大了阴极极化;镍和镍锰合金的电结晶都与三维连续成核理论相吻合,但加入氯化锰后电结晶成核速率常数增大,晶体向外生长速度和镍离子的扩散系数下降;电荷传递电阻增大,双电层电容下降.这些变化可能都与Mn(OH)2在阴极表面的吸附有关.","authors":[{"authorName":"潘秉锁","id":"89be4c0d-ffdf-4059-83b1-29a287120b02","originalAuthorName":"潘秉锁"},{"authorName":"牛明远","id":"e8e89794-309b-4d02-8014-dd55f02f9051","originalAuthorName":"牛明远"},{"authorName":"方小红","id":"1f21ca05-86c6-4c45-ac5b-44613a21a98b","originalAuthorName":"方小红"}],"doi":"","fpage":"1","id":"89d72238-9663-4077-836a-01b775acf018","issue":"10","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"cd35422d-d12d-46d4-814e-9d74e287cc07","keyword":"电沉积","originalKeyword":"电沉积"},{"id":"a71edc31-c032-4f97-969a-29a8bd4c0426","keyword":"镍锰合金","originalKeyword":"镍锰合金"},{"id":"7911755e-1c1a-4d3f-a317-73b8a90f45ca","keyword":"成核机理","originalKeyword":"成核机理"},{"id":"304d78a3-c7d7-4079-b851-d78a7be0d7ca","keyword":"阴极过程","originalKeyword":"阴极过程"}],"language":"zh","publisherId":"clbh200910001","title":"镍锰合金的电沉积行为","volume":"42","year":"2009"},{"abstractinfo":"对利用冲液装置和高频窄脉宽脉冲电流电铸所得到的镍锰合金试片进行了显微硬度的测试及拉伸试验,研究与分析了沉积电流密度对电铸层显微硬度和拉伸性能的影响.结果表明,随沉积电流密度的增大,由于电铸层锰含量升高和晶粒尺寸减小而使电铸镍锰合金的显微硬度和强度升高,延伸率降低.电铸纳米晶镍锰合金具有较高的显微硬度和强度.","authors":[{"authorName":"杨建明","id":"55cd7e65-3dde-4f44-89b4-e3028c74bb55","originalAuthorName":"杨建明"},{"authorName":"朱荻","id":"c2185328-cb88-49bb-800b-0a66c37464bc","originalAuthorName":"朱荻"},{"authorName":"曲宁松","id":"5ba3456c-6149-448f-a202-38ca8637f7ac","originalAuthorName":"曲宁松"}],"doi":"10.3969/j.issn.1004-244X.2004.06.003","fpage":"8","id":"4f62eea0-7c64-4674-9a68-5c23ddb7dda9","issue":"6","journal":{"abbrevTitle":"BQCLKXYGC","coverImgSrc":"journal/img/cover/BQCLKXYGC.jpg","id":"4","issnPpub":"1004-244X","publisherId":"BQCLKXYGC","title":"兵器材料科学与工程 "},"keywords":[{"id":"bae0a486-6594-417a-be33-572e3c7f0453","keyword":"电铸","originalKeyword":"电铸"},{"id":"11924861-e2f2-4910-9bbf-cdf9efa0d6d6","keyword":"脉冲电流","originalKeyword":"脉冲电流"},{"id":"313f2f44-234e-4526-bfe9-7f6bf74c188b","keyword":"镍锰合金","originalKeyword":"镍锰合金"},{"id":"917148a1-17ce-4e91-8fee-1ff322836ba7","keyword":"力学性能","originalKeyword":"力学性能"},{"id":"f5ea4ab8-a468-4457-a6de-0af2695a85e4","keyword":"纳米晶","originalKeyword":"纳米晶"}],"language":"zh","publisherId":"bqclkxygc200406003","title":"电铸纳米晶镍锰合金的性能研究","volume":"27","year":"2004"},{"abstractinfo":"利用一种新的电铸技术--游离粒子辅助磨电铸技术进行镍锰合金的电铸试验.验证了游离粒子的辅助摩擦研磨作用对镍锰合金电铸层的表面形貌、表面粗糙度、锰含量分布及电流效率的影响,并与传统电铸技术所制备的镍锰合金电铸层进行对比.结果表明:采用游离粒子辅助磨电铸技术所制备的镍锰合金电铸层外观光亮平整,表面粗糙度Ra由0.6μm降到0.05μm,晶粒得到了明显的细化,由微米级尺度降低到150nm以内;电流效率由80%左右增至96%;另外,通过调节阴极旋转速度可以改变电铸层中锰含量,随着阴极转速的提高电铸层中锰含量增加,当超过一定转速时,锰含量开始下降.","authors":[{"authorName":"李学磊","id":"0e4a20c2-6e32-450f-a493-0212668161c5","originalAuthorName":"李学磊"},{"authorName":"朱增伟","id":"a66608f6-84b1-44e2-834c-be4d61edc686","originalAuthorName":"朱增伟"},{"authorName":"朱荻","id":"2f194b42-9511-41b6-82b0-e6df00b0eb8f","originalAuthorName":"朱荻"}],"doi":"10.3969/j.issn.1001-4381.2010.12.004","fpage":"14","id":"73cc7634-ea79-4698-82d0-edef9d99704a","issue":"12","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"1159fb8d-6d7a-486f-921b-2af9b6b81e37","keyword":"电铸","originalKeyword":"电铸"},{"id":"13660a1c-f78a-43ad-b38c-d72cd1166bf5","keyword":"摩擦","originalKeyword":"摩擦"},{"id":"563a8c99-15ad-4960-8cc4-9f8dca65c7c6","keyword":"镍锰合金","originalKeyword":"镍锰合金"},{"id":"ba4bee67-36ac-43af-a3df-6fc1ce61c9b5","keyword":"游离粒子","originalKeyword":"游离粒子"}],"language":"zh","publisherId":"clgc201012004","title":"游离粒子辅助磨对镍锰合金电铸层表面质量及锰含量的影响","volume":"","year":"2010"},{"abstractinfo":"为了更好地控制镍锰合金的电铸过程、获得质量较好的电铸层,利用冲液式电铸沉积单元进行了镍和镍锰合金的脉冲电铸对比试验.试验发现,镍锰合金电铸时阳极上会产生疏松的黑色附着层.对提取的黑色粉末用扫描电镜进行能谱分析可知,该黑色附着层中含有较多的Mn和O,较少的Ni和很少的S.经化学分析和电化学理论分析可知,黑色附着层的成分为阳极上Mn2+发生氧化反应所形成的MnO2和阳极钝化所形成的少量Ni2O3.采取正确的过滤和沉淀措施后阳极黑色附着层对镍锰合金电铸过程不会产生明显的影响.","authors":[{"authorName":"杨建明","id":"ec60d118-3ffe-43f0-8513-b8aea766277b","originalAuthorName":"杨建明"},{"authorName":"朱荻","id":"9bc28af0-7aab-4087-a49e-7bf262a28bda","originalAuthorName":"朱荻"},{"authorName":"雷卫宁","id":"cde492c3-57e1-4535-ab88-75c2c35029d9","originalAuthorName":"雷卫宁"},{"authorName":"曲宁松","id":"5526e6a0-6d21-4a2b-ba1c-255d5605deae","originalAuthorName":"曲宁松"}],"doi":"10.3969/j.issn.1001-1560.2005.10.005","fpage":"15","id":"36fe29c2-a733-41b6-a1a6-9eff51c3c627","issue":"10","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"409ed69a-847b-4f45-8b50-ab695850a70f","keyword":"电铸","originalKeyword":"电铸"},{"id":"fb91a0f9-814d-4d96-bc54-e3e3cd3171c2","keyword":"镍锰合金","originalKeyword":"镍锰合金"},{"id":"50cb8e96-2d6e-485f-b176-3223a787349b","keyword":"阳极反应","originalKeyword":"阳极反应"}],"language":"zh","publisherId":"clbh200510005","title":"镍锰合金电铸中阳极现象的研究","volume":"38","year":"2005"},{"abstractinfo":"用于耐磨滑履胎体的镍锰合金在硫酸盐-氯化物电镀溶液中沉积,试验在室温下进行,pH在3.5～5之间,电流密度是0.8～1.2 A/dm2.比较系统地研究了镀液中[n(Mn2+)]/[n(Ni2+)+n(Mn2+)]比值对镍锰合金胎体成分的影响以及镍锰合金比例对胎体的表面洛氏硬度和耐磨性的影响.结果表明:镀液中[n(Mn2+)]/[n(Ni2+)+n(Mn2+)]摩尔比值为0.063时,镀层中锰的质量分数为0.1%,镀层的表面洛氏硬度是45±2HRC,用这种胎体配方研制的金刚石滑履的使用寿命超过4 a,证明镍锰合金是制作金刚石耐磨滑履的合适材料.","authors":[{"authorName":"李超群","id":"49ae79e2-8271-4b23-b34d-76e7e05f8e96","originalAuthorName":"李超群"},{"authorName":"李新海","id":"c40849c4-3632-4a2c-b4d6-4b26a06d785f","originalAuthorName":"李新海"},{"authorName":"王志兴","id":"7ee50b03-3bc4-48a2-83f2-7ad6d41d9041","originalAuthorName":"王志兴"},{"authorName":"郭华军","id":"b7325976-ed68-470e-bd8b-ceaaa36a7a98","originalAuthorName":"郭华军"}],"doi":"10.3969/j.issn.1671-6620.2008.01.010","fpage":"43","id":"789d9044-eafb-4f6d-8a32-ca4eed08e6ba","issue":"1","journal":{"abbrevTitle":"CLYYJXB","coverImgSrc":"journal/img/cover/CLYYJXB.jpg","id":"17","issnPpub":"1671-6620","publisherId":"CLYYJXB","title":"材料与冶金学报"},"keywords":[{"id":"ad2c9ccc-4004-419a-b547-d309a4ac26bc","keyword":"滑履","originalKeyword":"滑履"},{"id":"1a53a6cd-99da-4eff-9e5c-3a30ecef1337","keyword":"耐磨性","originalKeyword":"耐磨性"},{"id":"54d26a9c-9e9c-4c25-a43c-3eecc5800a18","keyword":"镍锰合金","originalKeyword":"镍锰合金"},{"id":"1da01267-23ed-45db-9c04-be9a63609053","keyword":"胎体材料","originalKeyword":"胎体材料"},{"id":"cd1a9ec6-cf35-4441-86e6-f34a187dd724","keyword":"金刚石","originalKeyword":"金刚石"}],"language":"zh","publisherId":"clyyjxb200801010","title":"电镀耐磨滑履的胎体性能和应用","volume":"7","year":"2008"},{"abstractinfo":"研究了镍锰钴合金中杂质氧的测定方法.针对金属锰高温下易挥发和吸附气体的特点,选择适宜的加热温度,使用锡片作为浴料,以锡囊包裹并装入腐蚀好的镍篮中,选择标准坩埚,用5kW加热电流进行试验,获得了满意的分析测定效果.对含氧0.018%的试样,分析精确度为4.6 %,加标回收率为94%～108%.","authors":[{"authorName":"周岭","id":"58029d9f-1cc7-4c8c-94cb-096fad86718a","originalAuthorName":"周岭"},{"authorName":"郑华","id":"8744a961-a634-4f70-be19-a5e9054251cc","originalAuthorName":"郑华"},{"authorName":"周海收","id":"69c9edc8-56b1-482f-bce4-5e383c8763cd","originalAuthorName":"周海收"}],"doi":"10.3969/j.issn.0258-7076.2002.04.012","fpage":"287","id":"7b7b6a03-b511-4a7c-8be6-83b2a4f27324","issue":"4","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"eada2000-7a65-4344-a5d3-c35d843b0e92","keyword":"镍锰钴合金","originalKeyword":"镍锰钴合金"},{"id":"a49128ba-e36b-4973-b18a-77c5437ef098","keyword":"氧","originalKeyword":"氧"},{"id":"b2ce57fc-42b2-4e97-a436-e38b156f452f","keyword":"测定仪器法","originalKeyword":"测定仪器法"}],"language":"zh","publisherId":"xyjs200204012","title":"镍锰钴合金中氧的测定方法研究","volume":"26","year":"2002"},{"abstractinfo":"建立了高锰酸钾电位滴定测定锰的方法,研究了不同合金中测定锰的条件.结果表明:在焦磷酸钠介质中,采用Pt指示电极和Ag参比电极指示滴定终点,用KMnO_4溶液滴定Mn(Ⅱ)为Mn(Ⅲ),测定6.00～30.00 mg Mn,相对误差≤±0.33%,加标准回收率在99.60%～100.40%.方法准确度高,重现性和选择性好,操作简便,终点敏锐,已应用于锰质量分数为7%～98%的银、铜、镍、锰等合金中锰的测定,结果满意.","authors":[{"authorName":"金娅秋","id":"6a80447b-28df-42fc-8c6d-bb8b75d0fa57","originalAuthorName":"金娅秋"},{"authorName":"朱利亚","id":"bbd3f12d-2e37-457c-a8cc-fc5d2d741c90","originalAuthorName":"朱利亚"},{"authorName":"安中庆","id":"d2e5b608-1064-470b-b4c0-83a94f376821","originalAuthorName":"安中庆"},{"authorName":"陈登权","id":"7abe2a1b-76c7-4225-bef8-4d693c36d090","originalAuthorName":"陈登权"},{"authorName":"管有祥","id":"431b9bf4-99a6-44c2-b8b2-60323dea4dd6","originalAuthorName":"管有祥"}],"doi":"10.3969/j.issn.1004-0676.2009.04.008","fpage":"33","id":"5996aa3e-724b-430e-b2de-752d31021e1d","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"20b137ab-607a-4a46-8198-53ce6a6618b7","keyword":"分析化学","originalKeyword":"分析化学"},{"id":"908020d9-aafc-4f6a-9987-9c189a6b6654","keyword":"电位滴定法","originalKeyword":"电位滴定法"},{"id":"a748bc0a-397a-496e-961c-88351031b4b3","keyword":"银、铜、镍、锰合金","originalKeyword":"银、铜、镍、锰合金"},{"id":"1810f63f-61a4-4afd-a6f0-da0c69c4ed4c","keyword":"锰","originalKeyword":"锰"}],"language":"zh","publisherId":"gjs200904008","title":"电位滴定法测定银、铜、镍、锰合金中的锰","volume":"30","year":"2009"},{"abstractinfo":"在Q235钢表面脉冲电镀Zn-Ni-Mn合金,镀液组成和工艺条件为:ZnSO4·7H2O 43.1 g/L,MnSO4·H2O 59.2 g/L,NiSO4·6H2O26.3 g/L,Na3C6H5O7·2H2O 176.5 g/L,NH4Cl 30 g/L,H3BO3 30 g/L,十二烷基硫酸钠(SDS) 0.1 g/L,pH 4.5～6.O,温度30℃,平均电流密度30 mA/cm2,脉冲占空比20％,脉冲周期1 ms,时间20 min.研究了pH对合金镀层元素组成、沉积速率、表面形貌和耐蚀性的影响.结果表明,随pH增大,沉积速率减小;镀层中锰含量升高,锌、镍含量降低;耐蚀性先增强后减弱.pH为5.0时,所得Zn-Ni-Mn合金镀层平整致密,Zn、Ni和Mn的质量分数分别为85.71％、5.03％和9.26％,中性盐雾试验96 h的保护等级为5级.与Zn-Ni合金镀层(Ni质量分数为12.88％)相比,Zn-Ni-Mn合金镀层的腐蚀电位正移了85 mV,腐蚀电流密度低了约2个数量级,耐蚀性更优.","authors":[{"authorName":"王心悦","id":"dc64163e-5739-476e-8ef8-04d42018b311","originalAuthorName":"王心悦"},{"authorName":"杨海丽","id":"4f2b9eb1-8db3-408a-a5d5-cc9012f2b4e3","originalAuthorName":"杨海丽"},{"authorName":"刘海鹏","id":"0fb162a5-dd29-4309-948d-c4f709319cf0","originalAuthorName":"刘海鹏"},{"authorName":"王雁利","id":"f4bc45d4-f694-4c6a-8d99-49bf468697e6","originalAuthorName":"王雁利"},{"authorName":"冯策","id":"533b9054-76c7-43cb-a739-06be81d1f2c4","originalAuthorName":"冯策"},{"authorName":"张志桐","id":"7538563c-fb95-41d8-b66b-7367f1870133","originalAuthorName":"张志桐"},{"authorName":"李运刚","id":"8995ab34-4ac3-454c-9bbd-e7943f8289c4","originalAuthorName":"李运刚"}],"doi":"","fpage":"449","id":"092b7a82-353d-427e-8850-a235ec401e8a","issue":"9","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"41c09129-4fb4-4f43-8027-593e011f44a0","keyword":"锌-镍-锰合金","originalKeyword":"锌-镍-锰合金"},{"id":"5fe0b1f2-3c76-4448-baa2-93df6befb597","keyword":"脉冲电镀","originalKeyword":"脉冲电镀"},{"id":"69ca3fa9-ca5e-4454-91e2-fb4878d33c74","keyword":"酸度","originalKeyword":"酸度"},{"id":"c3571d8d-ca60-464d-b684-589a9104a448","keyword":"沉积速率","originalKeyword":"沉积速率"},{"id":"3fa4d12b-d42b-4bc3-9161-f8a85ac69fd6","keyword":"表面形貌","originalKeyword":"表面形貌"},{"id":"2c619462-e734-4637-9150-83a8dd4ba552","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"ddyts201609003","title":"pH对脉冲电镀锌-镍-锰合金的影响","volume":"35","year":"2016"},{"abstractinfo":"用氩弧将铁、镍、稀土、锰直接或间接熔入铝硅合金表面,研究这些元素对含铁量为1.03%～6.92%的焊缝中铁相形态的影响.研究发现,稀土含量低时可抑制针状铁相;稀土含量大于一定量就会生成针状的Al-Si-Re-Ni-Fe相,该针状相的长度随稀土含量的增加而增加.铝硅合金中加入铁、锰、稀土后,熔敷金属中出现四瓣状Al-Si-Mn-Fe相.若加入等量的Fe、Ni,熔敷金属中会形成间断的Al-Si-Fe-Ni网状组织;若同时加入锰,除了生成网状结构外,还会同时存在四瓣状Al-Si-Mn-Fe相和三瓣状的Al-Si-Mn-Fe-Ni相.在铝硅合金中,单独加镍、同时加稀土和镍、同时加稀土和锰、同时加锰和镍均可很好地抑制针状铁相.锰、镍抑制针状铁相的效果明显优于稀土.","authors":[{"authorName":"陈冰泉","id":"ae889dce-d1e9-430f-8add-726ba5df8461","originalAuthorName":"陈冰泉"},{"authorName":"彭军波","id":"548e6099-5140-4856-8e04-6a9665a144a0","originalAuthorName":"彭军波"},{"authorName":"缪鄂","id":"4719c9cd-56f1-4b1c-8d68-3ff3de06a34d","originalAuthorName":"缪鄂"}],"doi":"10.3969/j.issn.1000-3738.2003.04.005","fpage":"14","id":"52d34e4c-866b-4905-bd86-1ef474f140e7","issue":"4","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"3cf22f3b-7c97-4f61-9392-d789df58c5d1","keyword":"稀土","originalKeyword":"稀土"},{"id":"ae9a4ddc-06ad-40d0-b8c9-92bfbe57cbe7","keyword":"锰","originalKeyword":"锰"},{"id":"0996f304-90d1-4bd9-8003-ba27ea7d42a6","keyword":"镍","originalKeyword":"镍"},{"id":"276ece5f-ed40-4c83-a808-b111d01d6f59","keyword":"铝硅合金","originalKeyword":"铝硅合金"},{"id":"147ec760-5f1f-4e1f-9360-7dc58aaf23ac","keyword":"氩弧","originalKeyword":"氩弧"},{"id":"9a1b2559-ffcb-4dcc-97be-b15278d1345d","keyword":"铁相形态","originalKeyword":"铁相形态"}],"language":"zh","publisherId":"jxgccl200304005","title":"稀土、镍、锰对铝硅合金熔敷金属中铁相形态的影响","volume":"27","year":"2003"},{"abstractinfo":"应用倒扭摆内耗仪、热机械分析仪和光学显微镜研究了碳和镍对铁-锰基减振合金γ→ε转变行为和阻尼性能影响.结果表明:碳增加γ→ε相变的阻力,降低合金的Ms温度,减少合金中ε马氏体的数量;碳的钉扎作用能够使合金中γ/ε相界面的滑移性能变差,从而恶化了合金的阻尼性能.镍降低了合金的相变温度,但不会对合金阻尼性能产生不利影响.","authors":[{"authorName":"李宁","id":"25c4c789-7e2a-4823-ac07-9498043d2239","originalAuthorName":"李宁"},{"authorName":"胥永刚","id":"618cbf78-bb84-489b-82cb-5d1891274956","originalAuthorName":"胥永刚"},{"authorName":"于学勇","id":"b5774e9c-8da6-48b6-aac6-7c5982252f74","originalAuthorName":"于学勇"},{"authorName":"邹红","id":"b1fd88e5-6b29-476d-b486-6e37b3fc68b4","originalAuthorName":"邹红"},{"authorName":"邱绍宇","id":"66333f48-b2e8-4b81-9f38-9991851105b0","originalAuthorName":"邱绍宇"}],"doi":"10.3969/j.issn.1000-3738.2006.03.003","fpage":"8","id":"4b047f7e-c1c1-45e1-aa56-ada3f8ed8a7e","issue":"3","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"5a53280e-6cc1-4d86-a518-22503b10617d","keyword":"阻尼性能","originalKeyword":"阻尼性能"},{"id":"d43cdfb3-7b79-4399-b75b-81ba84bb2f02","keyword":"相变","originalKeyword":"相变"},{"id":"b1ddb912-5b3e-4059-aa34-411aab19a2ff","keyword":"γ/ε相界","originalKeyword":"γ/ε相界"},{"id":"e25afc6e-9c19-4982-b3a8-37e1cb8b7ba4","keyword":"铁-锰合金","originalKeyword":"铁-锰合金"}],"language":"zh","publisherId":"jxgccl200603003","title":"碳、镍元素对铁-锰合金的阻尼性能与相变行为的影响","volume":"30","year":"2006"}],"totalpage":4359,"totalrecord":43590}