采用电场激活自蔓延高温燃烧合成(FASHS)技术制备了致密度高、且晶粒细小的TiC-Fe-Ni系梯度功能材料.外加电场通过焦耳加热效应及电流分配作用使蔓延波自持续下去,克服了SHS的热力学及动力学局限性,提高反应率;试验发现,电场促使梯度过渡层在宏观上呈均匀分布和稳定过渡;反应前沿的成分梯度是传质现象的驱动力,它促使Ni3Ti、Fe5C2的生成.电场通过增加电子和离子的运动速度,加快了离子的交换过程,使反应更加充分,生成物的成分更均匀.
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