为了提高孔洞结构聚丙烯(cellular PP)铁电驻极体的压电性能,采用高压气体膨化技术对材料进行了改性处理,并利用准静态和干涉仪测量方法,对经处理的cellular PP铁电驻极体薄膜的压电效应进行了研究.结果表明:气体膨化工艺能够明显提高cellular PP铁电驻极体薄膜的压电活性;这种突出的压电活性源于膨化膜杨氏模量Y的降低和电极化能力的提高;压电系数d33随频率的增加呈现下降趋势:从0.01Hz下的1200 pC/N降低到共振频率附近的350 pC/N;对于不同参数处理的样品,它们的共振频率在150~400 kHz;大多数样品的d33在0.2~10 kPa的范围内没有明显的变化,但是高于10 kPa,d33随之下降;cellu-lar PP铁电驻极体薄膜d33的热稳定性与非孔洞型PP驻极体薄膜的电荷储存热稳定性相当.
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