从发现钝化现象至今的近两个世纪,Fe钝化膜的结构和性质一直是电化学和材料科学的研究热点.简要概括了 Fe表面钝化膜研究的意义及历史,综述了Fe在不同溶液中通过不同方法形成钝化膜的结构与性质的研究过程及现状.在研究过程中已经提出过4种关于Fe在水溶液中形成钝化膜结构模型,但由于实验技术和方法的局限性,这些模型并未能真正反映Fe钝化膜的真实面貌.随着先进技术及方法的引入,对Fe钝化膜的微观结构、组成及防腐机制等的认识越来越深刻.
参考文献
| [1] | Uhlig H H.Passivity of Metals[M].Princeton :R.P. Frankenthal and J. Kruger,1983 |
| [2] | Davenport A.J.;Oblonsky L.J. .The Structure of the Passive Film That Forms on Iron in Aqueous Environments[J].Journal of the Electrochemical Society,2000(6):2162-2173. |
| [3] | Faraday M.Experimental researches in electricity[M].New York : Dover,1965 |
| [4] | Evans U R .The passivity of metals[J].Journal of the Chemical Society,1927,127:1020-1040. |
| [5] | 魏宝明.金属腐蚀理论及应用[M].北京:化学工业出版社,1984:124. |
| [6] | Szklarska Smialowska Z.Pitting corrosion of metals[A].Hous-ton,1986 |
| [7] | MAYNE J E O;Pryor M J.The mechanism of inhibition of corrosion of iron by chromic acid and potassium chromate[J].Journal of the Chemical Society,1949:1831-1835. |
| [8] | Cohen M .An electron diffraction study of films formed by sodium nitrite solution on iron[J].Journal of Physical Chemistry,1952,56:451-453. |
| [9] | Foley C L et al.Electron diffraction studies of active passive and transpassive oxide films formed on iron[J].Journal of the Electrochemical Society,1967,114:994-1001. |
| [10] | Bockris J O' M et al.The mechanism of the passivation of iron in neutral solutions:An ellipsometric and coulometric investigation[J].Electrochimica Acta,1971,16:1859-1894. |
| [11] | AKIMOV A G et al.Spectroscopic study of the surface of an iron electrode in a neutral solution[J].Zashchita Metallov,1976,12(02):167-169. |
| [12] | Revie R W et al.Degraded passive film on iron:application of Aüger electron spectroscopy[J].Surface Science,1975,52(03):664-669. |
| [13] | Revie R W et al.The passive film on iron:an application of Aüger electron spectroscopy[J].Journal of the Electrochemical Society,1975,122:1460-1466. |
| [14] | O'Grady W E et al.Interpretation of Mossbauer spectra of passive films on metals[J].Surface Science,1973,38:249-251. |
| [15] | Bloom M G et al.γ - Fe2O3 and the passivity of iron[J].Corrosion Science,1965,5:623-630. |
| [16] | Wagner C .Models for lattice defects in oxide layer on passivated iron and nickel[J].Physical Chemistry,1973,77:1090-1097. |
| [17] | Nagayama M;Cohen M .The anodic oxidation of iron in a neutral solution Ⅰ . The nature and composition of the passive film[J].Journal of the Electrochemical Society,1962,109:781-790. |
| [18] | Nagayama M;Cohen M .The anodic oxidation of iron in a neutral solution Ⅱ. Effect of ferrous ion and pH on the behavior of pas sive iron[J].Journal of the Electrochemical Society,1963,110:670-680. |
| [19] | Kruger J;Calvert J .Ellipsometric - potentiostatic studies of iron passivity Ⅰ anodic film growth in slightly basic solutions[J].Journal of the Electrochemical Society,1967,114:43-48. |
| [20] | Vetter K J .A general thermodynamic theory of the potential of passive electrodes and its influence on passive corrosion[J].Journal of the Electrochemical Society,1963,110:597-605. |
| [21] | Ho F C;Ord J L .The anodic oxide of iron: its component layers and their properties[J].Journal of the Electrochemical Society,1972,119:139-145. |
| [22] | Tsuru T;Haruyama S .A resistometric study of the passive film on an evaporated iron electrode[J].Corrosion Science,1976,16:623-635. |
| [23] | Sato N;Kudo K .Ellipsometry of the passive film on iron in neu tral solution[J].Electrochimica Acta,1971,16:447-462. |
| [24] | Sato N et al.The anodic oxide film on iron in neutral solution[J].Electrochimica Acta,1971,16:1909-1921. |
| [25] | Sato N et al.Anodic passivating films on iron in phosphate and borate solutions[J].Zeitschrift für Physikalische Chemie,1975,98:271-284. |
| [26] | Robinson J;Walsh F C .In situ synchrotron radiation x - ray techniques for studies of corrosion and protection[J].Corrosion Science,1993,35:791-800. |
| [27] | GuiJ;Devine T M .In situ vibrational spectra of the passive film on iron in buffered borate solution[J].Corrosion Science,1991,32:1105-1124. |
| [28] | O' Grady W E .Mossbauer study of the passive oxide film on iron[J].Journal of the Electrochemical Society,1980,127:555-563. |
| [29] | Kerkar M et al.In situ structual studies of the passive film on iron and iron/chromium alloys using x - ray adsorption spectroscopy[J].Faraday Discussions of the Chemical Society,1990,89:31-40. |
| [30] | Kruger J.Structural studies of passive films using surface EXAFS[A].New York:Elsevier Science,1983:163-168. |
| [31] | Long G G et al.EXAFS study of the passive film on iron[J].Journal of the Electrochemical Society,1983,130:240-242. |
| [32] | Long G G et al.Structure of passive films on iron using a new surface- EXAFS technique[J].Journal of Electroanalytical Chemistry,1983,150:603-610. |
| [33] | Davenport AJ.;Sansone M. .HIGH RESOLUTION IN SITU XANES INVESTIGATION OF THE NATURE OF THE PASSIVE FILM ON IRON IN A PH 8.4 BORATE BUFFER[J].Journal of the Electrochemical Society,1995(3):725-730. |
| [34] | Valeska Schroeder;Thomas M. Devine .Surface enhanced Raman spectroscopy study of the galvanostatic reduction of the passive film on Iron[J].Journal of the Electrochemical Society,1999(11):4061-4070. |
| [35] | Rubim J C;Dunwald J .Enhanced Raman scattering from passive films on silver - coated iron electrodes[J].Journal of Electroanalytical Chemistry,1989,258:327-344. |
| [36] | GuiJ;Devine T M .Obtaining surface - enhanced Raman spectra from the passive film on iron[J].Journal of the Electrochemical Society,1991,138:1376-1384. |
| [37] | Oblonsky L J;Devine T M .A surface enhanced Raman spectroscopic study of the passive films in borate buffer on iron nickel chromium and stainless steel[J].Corrosion Science,1995,37:17-41. |
| [38] | Oblonsky LJ.;Schroeder V.;Devine TM.;Virtanen S. .SURFACE ENHANCED RAMAN SPECTROSCOPY OF IRON OXIDE THIN FILMS - COMPARISON WITH THE PASSIVE FILM ON IRON[J].Journal of the Electrochemical Society,1997(5):1604-1609. |
| [39] | Schmuki P.;Davenport AJ.;Vitus CM.;Virtanen S. .IN SITU X-RAY ABSORPTION NEAR-EDGE SPECTROSCOPIC STUDY OF THE CATHODIC REDUCTION OF ARTIFICIAL IRON OXIDE PASSIVE FILMS[J].Journal of the Electrochemical Society,1996(2):574-582. |
| [40] | Kuroda K;etal .Electron diffraction study of the passive film on iron[J].Journal of the Electrochemical Society,1982,129:2163-2169. |
| [41] | Wells M F.Structural Inorganic Chemistry[M].Oxford:Claren don,1984 |
| [42] | Greaves C .A Powder neutron diffraction investigation of vacancy ordering and covalence[J].Journal of Solid State Chemistry,1983,49:325-333. |
| [43] | Shmakov AN.;Tsybulya SV.;Chuvilin AL.;Solovyeva LP.;Kryukova GN. .VACANCY ORDERING IN GAMMA-FE2O3 - SYNCHROTRON X-RAY POWDER DIFFRACTION AND HIGH-RESOLUTION ELECTRON MICROSCOPY STUDIES[J].Journal of Applied Crystallography,1995(2):141-145. |
| [44] | Ryan M P et al.An STM study of the passive film formed on iron in borate buffer solution[J].Journal of the Electrochemical Society,1995,142:L177-L179. |
| [45] | Castro P A et al.Surface electrochemical transformation on spinel iron oxide electrodes in aqueous solutions[J].Journal of the Chemical Society,Faraday Transactions,1996,92:3371-3379. |
| [46] | Tamaura Y;Tabara M .Complete reduction of carbon dioxide to carbon using cation- excess magnetite[J].Nature,1990,346:255-256. |
| [47] | HallEL;Berkowitz A E.Microstructural defects in particles[J].Journal of Materials Research,1986(01):836-844. |
| [48] | Berkowitz A E et al.Microstructure relaxation and print through in y - Fe2O3 particles[J].Journal of Applied Physics,1985,57:3928-3933. |
| [49] | Margulies D et al.Origin of the anomalous magnetic behavior in single crystal Fe3O4 films[J].Physical Review Letters,1997,79:5162-5165. |
| [50] | Fitzgerald A G;May T G .Defects in epitaxial ferrite films grown by chemical vapour deposition[J].Thin Solid Films,1976,35:201-213. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%