在小规模流化床(FBC)中燃烧一种低S高Cl煤1000 h后,对放置于接近沸腾床位置的A210-C碳钢管腐蚀情况进行分析.发现在碳钢管表面温度为470℃～560℃的区域腐蚀产物(主要为Fe2O3)严重剥落.剥落的腐蚀产物表面覆盖一层沉积盐,部分区域发现有(K,Na)Cl.对残留在钢管表面的腐蚀层进行分析,发现在腐蚀层-碳钢界面或其附近的基体中出现局部氯化,导致形成FeCl2层;局部快速腐蚀,形成向基体一侧的腐蚀突体;形成内部空洞这三种腐蚀形态.并对此现象的产生及Cl2的影响机制进行了详细探讨.
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