采用高纯铝和硅(＞99.99wt%)配制Al-10%Si二元合金,经三元钠盐变质,研究合金中共晶硅相.结果表明,铝硅合金共晶凝固时,硅相滞后于铝相结晶.进行钠盐变质处理后,共晶凝固时硅相滞后更加明显,并使之由片状转变为纤维状.钠盐变质后的共晶硅中有较多的孪晶,孪晶轴为(111)Si,孪晶方向为(211)Si,共晶两相的位向关系符合[100]Al∥[110]Si.钠盐变质后的共晶硅以孪晶沟槽(TPRE)长大机制进行分枝、细化和弯曲,从而证明孪晶沟槽长大机制是产生变质结构的重要途径.
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