基于氰酸酯树脂(CE)和磷酸铝( AlPO4)优良的综合性能,采用“复合技术”,设计并制备了AlPO4/CE复合材料,研究了不同偶联剂和AlPO4含量对AlPO4/CE复合材料的热性能、介电性能和吸湿性能的影响.研究结果表明,不同偶联剂对磷酸铝和CE之间的界面作用力影响不同.AlPO4(KH-550)和AlPO4( KH-560)与CE间的界面作用力稍高于AlPO4(H-2),并且AlPO4( KH-550)/CE复合材料的综合性能最佳；当加入适当含量AlPO4( KH-550)时,AlPO4(KH-550)/CE复合材料具有比纯CE树脂更佳的综合性能.
参考文献
| [1] | Guozheng Liang;Zengping Zhang;Jieying Yang .BMI Based Composites With Low Dielectric Loss[J].Polymer bulletin,2007(2):269-278. |
| [2] | HUANG P Z;GU A J;LIANG G Z et al.Dielectric properties of hyperbranched poly (phenylene oxide) /cyanate ester resins[J].Journal of Applied Polymer Science,2011,121(04):2113-2122. |
| [3] | Caifei Han;Aijuan Gu;Guozheng Liang;Li Yuan .Carbon nanotubes/cyanate ester composites with low percolation threshold,high dielectric constant and outstanding thermal property[J].Composites, Part A. Applied science and manufacturing,2010(9):1321-1328. |
| [4] | WU H Y;GU A J;LIANG G Z et al.Novel constant gradient carbon nanotubes/cyanate ester composites with high constant and extremely low dielectric loss[J].Journal of Materials Chemistry,2011,21(18):14838-14848. |
| [5] | Dona Mathew;C. P. Reghunadhan Nair;K. Krishnan;K. N. Ninan .Catalysis of the Cure Reaction of Bisphenol A Dicyanate. A DSC Study[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(8):1103-1114. |
| [6] | Xia Sheng;Mufit Akinc;Michael R. Kessler .The Effects of Alumina and Silica Nanoparticles on the Cure Kinetics of Bisphenol E Cyanate Ester[J].Polymer engineering and science,2010(6):1075-1084. |
| [7] | 杨洁颖,梁国正,王结良,任鹏刚.氰酸酯/线性酚醛/环氧树脂三元体系的研究[J].航空学报,2003(05):462-465. |
| [8] | Aijuan Gu .High performance bismaleimide/cyanate ester hybrid polymer networks with excellent dielectric properties[J].Composites science and technology,2006(11/12):1749-1755. |
| [9] | Minfeng Zeng;Cuiyun Lu;Baoyi Wang .Free volume hole size of Cyanate ester resin/Epoxy resin interpenetrating networks and its correlations with physical properties[J].Radiation Physics and Chemistry,2010(9):966-975. |
| [10] | Fan J.;Hu X.;Yue CY. .Static and dynamic mechanical properties of modified bismaleimide and cyanate ester interpenetrating polymer networks[J].Journal of Applied Polymer Science,2003(8):2000-2006. |
| [11] | FANG T;SHIMP DA .Polycyanate esters:science and applications[J].Progress in Polymer Science,1995,20(01):61-118. |
| [12] | 张志强,马琦,张宝柱,张智敏.有机-无机杂化材料的制备技术和应用前景[J].应用化工,2005(07):389-393. |
| [13] | 徐曼,曹晓珑,俞秉莉.纳米SiO2/环氧树脂复合体系性能研究--（Ⅱ）复合材料的介电特性和力学特性[J].高分子材料科学与工程,2005(01):156-159. |
| [14] | KRISCGWUTZ J J.Encyclopedia of polymer science and engineering,vol.5[M].New York:wiley,1990 |
| [15] | 李文峰 .改进的卤化氰-酚法合成氰酸酯研究[D].西安:西北工业大学,2004. |
| [16] | Hann-Jang Hwang;Chun-Hung Li;Chun-Shan Wang .Dielectric and thermal properties of dicyclopentadiene containing bismaleimide and cyanate ester.Part IV[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(4):1291-1299. |
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