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片状羰基铁具有高的饱和磁化强度和一定的平面各向异性,可突破Snoek限制,在微波吸收领域具有很好的应用前景.本文以球状羰基铁粉为原料,机械球磨制备了片状羰基铁,并根据球磨钢珠配比的改变获得形貌和电磁性能各异的片状羰基铁:随着钢球平均直径的减小,羰基铁片状结构逐渐增多,片状尺寸增大,片层厚度变薄,吸波性能提高;当采用4 mm钢球进行球磨时,片状羰基铁具有最佳吸波性能,其复磁导率的实部和虚部在2 GHz时可达到2.8773和0.9493;涂层厚度为2 mm时,反射率损耗在9.1 GHz处达到最大值-35 dB,小于-10 dB频带宽为7.429 GHz.

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