缓蚀剂的作用机理与缓蚀剂分子在金属表面形成的自组装单分子膜及其作用密切相关.利用扫描隧道显微镜(STM)可以实时、原位、三维实空间观察原子/分子的技术优势,在分子水平上认识金属-缓蚀剂之间的相互作用,对于金属腐蚀科学的理论研究具有十分重要的意义.本文简要介绍了STM对部分常用金属表面有机缓蚀剂自组装单分子膜的结构、分子取向、晶面结构效应等方面的最新研究进展.
参考文献
| [1] | Ramachandran S;Tsai B-L;Blanco M et al.Self-assembled monolayer mechanism for corrosion inhibition of iron by imidazolines[J].Langmuir,1996(12):6419-6428. |
| [2] | Kunitsugu Aramaki .Protection of iron corrosion by ultrathin two-dimensional polymer films of an alkanethiol monolayer modified with alkylethoxysilanes[J].Corrosion Science,1999(9):1715-1730. |
| [3] | 杨武;顾溶祥;黎樵燊.金属的局部腐蚀[M].北京:化学工业出版社,1995 |
| [4] | Hairston D W .Rustling up corrosion inhibitors[J].Chemical Engineering,1996,103(03):65-68. |
| [5] | Gewirth A A;Niece B K .Electrochemical applications of in situ scanning tunneling microscopy[J].Chemical Reviews,1997,97(04):1129-1162. |
| [6] | Cho K;Kishimoto J;Hashizume T et al.An observation of benzotriazole (BTA) adsorption on Cu(110)by the ultra high vacuum (UHV)-scanning tunneling microscope (STM) and low energy electron diffraction(LEED)[J].Japanese Journal of Applied Physics Part 2,1994(33):1125-128. |
| [7] | Vogt M R;Polewska W;Magnussen O M et al.In situ STM study of (100) Cu electrodes in sulfuric acid solution in the presence of benzotriazole[J].Journal of the Electrochemical Society,1997,144(05):L113-116. |
| [8] | Biggin M E;Gewirth A A .Infrared studies of benzotriazole on copper electrode surfaces: role of chloride in promoting reversibility[J].Journal of the Electrochemical Society,2001,148(05):C339-347. |
| [9] | Sugimasa M;Wan L-J;Inukai J et al.Adlayers of benzotriazole on Cu (110), (100), and (111) in HClO4 solution: in situ scanning tunneling microscopy study[J].Journal of the Electrochemical Society,2002,109(10):E367-373. |
| [10] | Tornkvist C;Thierry D;Bergman J et al.Methyl substitution in benzotriazole and its influence on surface structure and corrosion inhibition[J].Journal of the Electrochemical Society,1989,136(01):58-64. |
| [11] | Yan C W;Lin H C;Cao C N .Invastigation of inhibition of 2-mercaptobenzotriazole for copper corrosion[J].Electrochimica Acta,2000,45(17):2815-2821. |
| [12] | Sung M M;Sung K;Kim C G et al.Self-assembled monolayers of alkanethiols on oxidized copper surface[J].Journal of Physical Chemistry B,2000,104(10):2273-2277. |
| [13] | O.Azzaroni;M.Cipollone;M.E.Vela;R.C.Salvarezza .Protective Properties of Dodecanethiol Layers on Copper Surfaces: The Effect of Chloride Anions in Aqueous Environments[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(5):1483-1487. |
| [14] | Laibinis P E;Whitesides G M .Self-assembled monolayers of n-alkanethiolates on copper are barrier films that protect the metal against oxidation by air[J].Journal of the American Chemical Society,1992,114(23):9022-9028. |
| [15] | Driver SM.;Woodruff DP. .Adsorption structures of 1-octanethiol on Cu(111) studied by scanning tunneling microscopy[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(16):6693-6700. |
| [16] | Loepp G;Vollmer S;Witte G et al.Adsorption of heptanethiolon Cu(110)[J].Langmuir,1999,15(11):3767-3772. |
| [17] | Haneda R;Aramaki K .Protective films on copper by multistep modification of an alkanethiol monolayer with chlorosilanes and alkanediol[J].Journal of the Electrochemical Society,1998,145(08):2786-2791. |
| [18] | Cheng L;Bocarsly A B;Bernasek S L et al.Coadsorption of ethanethiol with sulfur, oxygen, and water on the Fe(100) surface[J].Langmuir,1996,12(02):392-401. |
| [19] | Volmer M;Reynders B;Stratmann M .Anbindungsverhalten organischer monomere auf eisenoberfl chen und korrosion der durch die anbindung chemisch modifizierten oberfl chen[J].Werkstoffe und Korrosion,1991,42(01):19-34. |
| [20] | Kong DS.;Chen SH.;Wan LJ.;Han MJ. .The preparation and in situ scanning tunneling microscopy study of Fe(110) surface[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(6):1954-1957. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%