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La-Mg-Ni系贮氢合金是新开发的大容量MH-Ni电池负极材料,但其市场化应用的瓶颈在于循环寿命太短.本文综述了改善La-Mg-Ni系(AB3-3.5型)贮氢合金循环寿命的方法,介绍了目前研究进展,讨论了La-Mg-Ni系贮氢合金的循环寿命与各种因素之间的关系,并对La-Mg-Ni系(AB3-3.5型)合金未来发展作了展望.

参考文献

[1] Chen J et al.Hydrogen storage alloys with PuNi-type structure as metal hydride electrodes[J].Electrochemical and Solid-State Letters,2000,3(06):249.
[2] Kohno T.;Yoshida H. .Hydrogen storage properties of new ternary system alloys: La_2MgNi_9, La_5Mg_2Ni_(23), La_3MgNi_(14)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(2):L5-L7.
[3] Pan H G et al.A study of the structural and electrochemical properties of La0.7 Mg0.3 (Ni0.85Co0.15)x(x=2.5~5) hydrogen storage alloys[J].Journal of the Electrochemical Society,2003,150(05):A565.
[4] Pan Hongge et al.An investigation on the structural and electrochemical properties of La0.7Mg0.3(Ni0.85Co0.15)x(x=3.15~3.80) hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2003,351:228.
[5] Liu Y F et al.Effect of Co content on the structural and electrochemical properties of the La0.7Mg0.3Ni3.4-xMn0.1Cox hydride alloys:I.The structure and hydrogen storage[J].Journal of Alloys and Compounds,2004,365:246.
[6] Liu Y F et al.The effect of Mn substitution for Ni on the structural and electrochemical properties of La0.7Mg0.3Ni2.55-x Co0.45Mnx hydrogen storage electrode alloys[J].International Journal of Hydrogen Energy,2004,29:228.
[7] Liao B et al.A study on the structure and electrochemical properties of La2Mg(Ni0.95M0.05)9(M=Co,Mn,Fe,Al,Cu,Sn) hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2004,376:186.
[8] Zhang Yang-Huan et al.Investigation on the microstructure and electrochemical performances of La2Mg(Ni0.85Co0.15)9Bx(x=0~0.2) hydrogen storage electrode alloys prepared by casting and rapid quenching[J].Journal of Alloys and Compounds,2004,379:298.
[9] 唐睿,刘丽琴,柳永宁,于光,朱杰武,刘晓东.La0.8-xRExMg0.2Ni3.2Co0.6储氢合金的结构及电化学性能[J].中国有色金属学报,2005(07):1057-1061.
[10] 刘丽琴,唐睿,柳永宁.稀土元素对La0.8 Mg0.2 Ni2.8 Co0.6 储氢合金性能的影响[J].中国有色金属学报,2003(04):871-875.
[11] Tang R .Study on the microstructure and the electrochemical properties of Ml0.7Mg0.2Ni2.8Co0.6 hydrogen storage alloy[J].International Journal of Hydrogen Energy,2003,28:815.
[12] Sakai T;Kato A et al.Studies on the electrochemical properties of MlNi Co Al hydride[J].Journal of the Less-Common Metals,1991,172-174:1175.
[13] Adzic G et al.Cerium content and cycle life of multicomponent AB hydride electrodes[J].Journal of the Electrochemical Society,1995,142:3429.
[14] Pan Hongge.Effect of the substitution of PR for LA on the microstructure and electrochemical properties of La0.7-x Prx Mg0.3Ni2.45Co0.75Mn0.1Al0.2(x=0~0.3) hydrogen storage electrode alloys[J].International Journal of Hydrogen Energy
[15] Pan Hongge et al.Effect of the cerium content on the structural and electrochemical properties of the La0.7-xCexMg0.3 Ni2.875Mn0.1Co0.525(x=0~0.5) hydrogen storage alloys[J].Journal of Alloys and Compounds,2004,373:237.
[16] Zhang X B et al.Effect of La/Ce ratio on the structure and electrochemical characteristics of La0.7-xCexMg0.3Ni2.5Co0.5(x=0.1~0.5) hydrogen storage alloys[J].Electrochimica Acta,2005,50:1957.
[17] Pan Hongge et al.The effect of substitution of Zr for La on the electrochemical properties of La0.7-xZrxMg0.3Ni2.45Mn0.1Co0.75Al0.2 hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2005,397:269.
[18] Liu Yongfeng et al.Cycling durability and degradation behavior of La-Mg-Ni-Co-type metal hydride electrodes[J].Journal of Alloys and Compounds,2005,395:291.
[19] Liu Yongfeng et al.Investigation on the characteristics of La0.7Mg0.3Ni2.65Mn0.1Co0.75+x(x=0~0.85) metal hydride electrode alloys for Ni/MH batteries (Part Ⅱ).Electrochemical performances[J].Journal of Alloys and Compounds,2005,388:109.
[20] Wang Dahui et al.Phase structure and electrochemical properties of La0.67Mg0.33Ni3.0-xCox(x=0,0.25,0.5,0.75) hydrogen storage alloys[J].Journal of Alloys and Compounds,2006,413:193.
[21] Sakai T et al.Metal hydride anodes for nickel-hydrogen secondary battery[J].Journal of the Electrochemical Society,1990,137:795.
[22] Pan Hongge et al.Electrochemical properties of the La0.7Mg0.3Ni2.65-xCo0.75Mn0.1Alx(x=0~0.5)hydrogen storage alloy electrodes[J].Journal of the Electrochemical Society,2005,152(02):A326.
[23] Tang Rui et al.Effect of substitution for Co on the hydrogen storage characteristics of Ml0.8Mg0.2Ni3.2Co0.6-xAlx[J].J Intermetallics,2006,14:361.
[24] Zhang Pang.Effect of Al and W substitution for Ni on the microstructure and electrochemical properties of La1.3Mg0.7Ni9-x(Al0.5W0.5)x hydrogen storage alloys[J].International Journal of Hydrogen Energy
[25] Zhang X B et al.Crystallographic and electrochemical characteristics of La0.7Mg0.3Ni3-x(Al0.5Mo0.5)x(x=0~0.4) hydrogen storage alloys[J].Electrochimica Acta,2005,50:3407.
[26] Pan Hongge et al.An electrochemical study of La0.4Ce0.3Mg0.3Ni2.975-xMnxCo0.525(x=0.1~0.4) hydrogen storage alloys[J].Journal of Alloys and Compounds,2004,376(1-2):196.
[27] Pan Hongge et al.Structure and electrochemical properties of La0.7Mg0.3Ni2.45-xCo0.75Mn0.1Al0.2Wx(x=0,0.15) hydrogen storage alloys[J].International Journal of Hydrogen Energy,2006,31:517.
[28] Guo Jin et al.Effect of Co and Mn on the electrochemical properties of La0.7Mg0.3Ni2(Co+ Mn) alloys[J].Journal of Alloys and Compounds,2005,390(1-2):301.
[29] Liao B et al.A study on the structure and electrochemical properties of La2Mg(Ni0.95M0.05)(M=Co,Mn,Fe,Al,Cu,Sn) hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2004,376:186.
[30] Zhang Yang-huan et al.The cycle stabilities of the as-cast and quenched La2Mg(Ni0.85Co0.15)9 Mx (M= B,Cr,Ti;x=0,0.1)hydrogen storage alloys[J].Journal of Alloys and Compounds,2005,398:178.
[31] Zhang Yang-Huan et al.Microstructure and electrochemical performances of La0.7Mg0.3Ni2.55-xCo0.45Mx(M=Cu,Cr,Al;x=0~0.4) hydrogen storage alloys prepared by casting and rapid quenching[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2007,458:67.
[32] Li CJ.;Wang XL. .The relations between the microstructure and the capacity decay rate of MLNi3.8Co0.6Mn0.55Ti0.05 alloy. I. Capacity decay rate measurements[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):242-245.
[33] Pan Hongge et al.Effects of annealing temperature on structure and the electrochemical properties of La0.7 Mg0.3 Ni2.45Co0.75Mn0.1Al0.2 hydrogen storage alloy[J].Journal of Alloys and Compounds,2005,397(1-2):306.
[34] Hongge Pan;Yongfeng Liu;Mingxia Gao;Yunfeng Zhu;Yongquan Lei;Qidong Wang .A study on the effect of annealing treatment on the electrochemical properties of La_(0.67)Mg_(0.33)Ni_(2.5)Co_(0.5) alloy electrodes[J].International journal of hydrogen energy,2003(1):113-117.
[35] Zhang Faliang et al.Effect of annealing treatment on structure and electrochemical properties of La0.67Mg0.33Ni2.5Co0.5 ailoy electrodes[J].Journal of Power Sources,2005,150:247.
[36] Kazuhide Tanaka;Yoshisada Kanda .Improvement of hydrogen storage properties of melt- spun Mg-Ni-RE alloys by nanocrystallization[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):521-525.
[37] Zhang Yang-huan et al.The effects of rapid quenching on the microstructures and electrochemical properties of low-Co AB5-type electrode alloy[J].Journal of Alloys and Compounds,2004,376:275.
[38] Han Shumin;Zhang Zhong;Li Yuan;Jing Tianfu;Wang Xiaotie .The effect of vacuum evaporation plating on phase structure and electrochemical properties of AB{sub}5-5 mass% LaMg{sub}3 composite alloy[J].Electrochimica Acta,2005(28):5491-5495.
[39] Chen Yun et al.Electrochemical properties of the ball-milled La1.5Ca0.2Mg14Ni3+xwt% Ni composites (x = 0,50,100,200)[J].Journal of Alloys and Compounds,2003,354:120.
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