对高熔点聚碳硅烷的合成反应条件进行了较为详细的研究,并通过改变化学反应的温度、压力和反应时间制备出了熔点高达380℃、数均分子量Mn＞3 000、陶瓷收率达79%(质量分数)以上的陶瓷先驱体聚合物.该先驱体溶解性能好,并具有良好的纺丝性能.文中还利用IR、TG-DTA等手段对该先驱体的热解机理进行了初步探讨.
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