采用溶胶凝胶法,以正硅酸乙酯和酚醛树脂为原料,在草酸和六次甲基四胺的催化作用下,制备出了不含硫和氯等有害杂质的均相碳化硅先驱体,并在特定条件下,对所得先驱体进行烧结,使之转化为陶瓷.结果表明,溶胶凝胶法制得的先驱体呈黄色透明的玻璃态,其微观组成为几十纳米的微粒,树脂与SiO2可能通过氢键相互作用,有利于树脂在先驱体中均匀分布而形成均相先驱体,其陶瓷产率为78%;另外硝酸镍的加入对先驱体烧结过程中β-SiC的生成起到明显的促进作用.
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