采用DSC方法研究RTM专用双马来酰亚胺树脂的固化动力学模型与固化动力学参数.用恒温和动态两种方法分析其固化反应;采用Melak方法和Kissinger方法进行数据处理.结果表明,RTM专用双马来酰亚胺树脂的固化动力学模型符合n级固化反应方程,用Melak计算方法建立的方程较好地描述了其固化过程,且与实验数据拟合结果较好.
参考文献
| [1] | Fontana Q P V .Viscosity: thermal history treatment in resin transfer moulding process modeling[J].Composites Part A:Applied Science and Manufacturing,1998,29:153-158. |
| [2] | 陈继荣;王井岗 等.改性双马来酰亚胺树脂的固化工艺研究[J].玻璃钢/复合材料,1998,3(03):7-9. |
| [3] | Shin D.D.;Hahn H.T. .A consistent cure kinetic model for AS4/3502 graphite/epoxy[J].Composites, Part A. Applied science and manufacturing,2000(9):991-999. |
| [4] | 阎业海,赵彤,余云照.复合材料树脂传递模塑工艺及适用树脂[J].高分子通报,2001(03):24-35. |
| [5] | Boey FYC.;Qiang W. .Experimental modeling of the cure kinetics of an epoxy-hexaanhydro-4-methylphthalicanhydride (MHHPA) system[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(6):2081-2094. |
| [6] | Freddy Y C;Boey X L;Modeling the curing kinetics for a modified Bismaleimide resin .Journal of Polymer Science[J].Polymer Chemistry,2000,38:907-913. |
| [7] | Goodwin A A .The curing kinetics of a modified bismaleimide[J].Polymer International,1993,32(01):87-92. |
| [8] | Melek J .The kinetic analysis of non-isothernal data[J].Thermochimica Acta,1992,200:257-269. |
| [9] | Kissiger D E .Reaction kinetic in differential thermal analysis[J].Analytical Chemistry,1957,29(11):1702-1706. |
| [10] | Ozawa T .Kinetic analysis of derivative curves in thermal analysis[J].Journal of Thermal Analysis,1970,2:301-324. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%