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采用铸锭冶金法制备了 Al-6.0Zn-2.0Mg-0.12Zr 和 Al- 6.0Zn - 2.0Mg - 0.2Sc - 0.12Zr 两种合金板材,以 Al-Mg-Sc-Zr焊丝为焊接填充材料,对3 mm厚的上述两种合金板材进行氩弧焊接,之后对两种接头的显微组织和力学性能进行对比研究.结果表明:第一,微量Sc可以显著提高Al-Zn-Mg-Zr合金基材的拉伸性能,基材强度的提高来源于晶粒细化强化、Al3(Sc,Zr)粒子的析出强化和Al3(Sc,Zr)粒子引起的亚结构强化;第二,焊接过程中,不含 Sc 的合金焊接接头热影响区内η相(MgZn2)粒子和晶粒明显粗化,含 Sc的合金焊接接头热影响区内η相(MsZn2)粒子也明显粗化,但晶粒大小没有明显变化,由于Al3(Sc、Zr)粒子稳定性高,不容易粗化和团聚,对位错和亚晶界仍然起钉扎作用,热影响区仍然保持未再结晶组织,过时效软化现象相对于传统的铝镁合金来说不是很严重;第三,微量 Sc 可以明显提高 Al-Zn-Mg-Zr 合金焊接接头的强度,与不加 Sc 的合金焊接接头相比,添加Sc的合金拉伸强度从395 MPa提高到447 MPa,强度系数从 0.7 提高到0.8.强度的提高主要来源于晶粒细化强化、Al3(Sc,Zr)粒子的析出强化和由于Al3(Sc,Zr)粒子的高稳定性导致的的抗热循环软化能力的提高.

参考文献

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