以正硅酸乙酯和含有亚脲基的桥联硅烷为前驱体,以十六烷基三甲基溴化铵为模板剂,在碱性条件下制备了具有"蠕虫状"双介孔孔道结构和高比表面积的杂化介孔二氧化硅材料,并采用XRD、FTIR、NMR、TEM、SEM等手段对制备的材料进行表征.研究发现,亚脲基均匀地嵌入到介孔孔壁中,随孔壁中亚脲基基团含量的增加,介孔二氧化硅的有序性下降,比表面积减小.
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