为了得到具有优良的分散性和导电性的碳气凝胶,研究了碳气凝胶的硝酸氧化改性温度对碳气凝胶的结构和性能的影响.通过FTIR、XPS、Zeta电位、XRD和N2等温吸附-脱附等技术对样品进行表征,结果表明:硝酸氧化改善分散性的机理在于对碳气凝胶表面的含氧官能团数量的改变,而且氧化温度越高,含氧官能团的数量就越多,碳气凝胶的分散性就越好;与此相反,较低温度的氧化处理有利于保持碳气凝胶的导电性(40℃,87.7%),而高温氧化由于易使碳气凝胶的微孔迅速增多从而导致其电导率急剧下降(100℃,2.5%).
参考文献
[1] | Tamon H.;Mikami M.;Okazaki M.;Ishizaka H. .POROUS STRUCTURE OF ORGANIC AND CARBON AEROGELS SYNTHESIZED BY SOL-GEL POLYCONDENSATION OF RESORCINOL WITH FORMALDEHYDE[J].Carbon: An International Journal Sponsored by the American Carbon Society,1997(6):791-796. |
[2] | Pekala R W .Organic aerogels from the polymerization of resorcinol with formaldehyde[J].Journal of Materials Science,1989,24(09):3221-3227. |
[3] | Hosoya M;Reynolds G;DresselhausM S et al.Formation of buried Sb dopant profiles in silicon by pulsed laser epitaxy[J].Journal of Materials Research,1993,8(04):811-819. |
[4] | Pekala RW.;Alviso CT.;Tran TD.;Mayer ST.;Miller JM.;Dunn B.;Farmer JC. .Carbon aerogels for electrochemical applications[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):74-80. |
[5] | Shaker Haji;Can Erkey .Removal of dibenzothiophene from Model Diesel by Adsorption on Carbon Aerogels for Fuel Cell Applications[J].Industrial & Engineering Chemistry Research,2003(26):6933-6937. |
[6] | Yang WJ;Wu DC;Fu RW .Effect of surface chemistry on the adsorption of basic dyes on carbon aerogels[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2008(2/3):118-124. |
[7] | Saliger R.;Herta C.;Fricke J.;Fischer U. .High surface area carbon aerogels for supercapacitors[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(1):81-85. |
[8] | Fang B;Wei Y Z;Kumagai M .Modified carbon mat erials for high-rate EDLCs application[J].Journal of Power Sources,2006,155(02):487-491. |
[9] | Hilding J.;Grulke EA.;Zhang ZG.;Lockwood F. .Dispersion of carbon nanotubes in liquids [Review][J].Journal of Dispersion Science and Technology,2003(1):1-41. |
[10] | 肖英,李兰英,张瑞,戴晓雁.获取优良分散性炭黑的表面硝酸氧化[J].材料科学与工艺,2005(01):75-77,81. |
[11] | Katsumi Kamegawa;Keiko Nishikubo;Masaya Kodama;Yoshio Adachi;Hisayoshi Yoshida .Oxidative degradation of carbon blacks with nitric acid II. Formation of water-soluble polynuclear aromatic compounds[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(9):1447-1455. |
[12] | 谢华清.壳状碳纳米颗粒的制备和分散[J].新型炭材料,2007(01):80-83. |
[13] | 龙东辉,张洁,杨俊和,胡子君,李同起,成果,张睿,凌立成.苯酚-间甲酚-糠醛基炭气凝胶的制备及微结构控制[J].新型炭材料,2008(02):165-170. |
[14] | Linqin Jiang;Lian Gao;Jing Sun .Production of aqueous colloidal dispersions of carbon nanotubes[J].Journal of Colloid and Interface Science,2003(1):89-94. |
[15] | Catalao R A;Maldonado-Hodar F J;Fernandes A et al.Reduction of with metal-doped carbon aerogels[J].Applied Catalysis B:Environmental,2009,88(1/2):135-141. |
[16] | Anning Zhou;Xiaoliang Ma;Chunshan Song .Effects of oxidative modification of carbon surface on the adsorption of sulfur compounds in diesel fuel[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2009(3/4):190-199. |
[17] | Anning Zhou;Xiaoliang Ma;Chunshan Song .Liquid-Phase Adsorption of Multi-Ring Thiophenic Sulfur Compounds on Carbon Materials with Different Surface Properties[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(10):4699-4707. |
[18] | Polovina M.;Kaluderovic B.;Dekanski A.;Babic B. .SURFACE CHARACTERIZATION OF OXIDIZED ACTIVATED CARBON CLOTH[J].Carbon: An International Journal Sponsored by the American Carbon Society,1997(8):1047-1052. |
[19] | Yu-Qing Wang;Hema Viswanathan;Ahmad Ali Audi;Peter M.A.Sherwood .X-ray Photoelectron Spectroscopic Studies of Carbon Fiber Surfaces.22.Comparisoin between Surface Treatment of Untreated and previously Surface-Treated Fibers[J].Chemistry of Materials,2000(4):1100-1107. |
[20] | Z.-M.Wang;N.Yamashita;Z.-X.Wang;K.Hoshinoo;H.Kanoh .Air oxidation effects on microporosity,surface property,and CH4 adsorptivity of pitch-based activated carbon fibers[J].Journal of Colloid and Interface Science,2004(1):143-150. |
[21] | Vinke P;Eijk M V;Verbree M et al.Modification of the surfaces of a gasactivated carbon and a chemically activated carbon with nitric acid,hypochlorite,and ammonia[J].Carbon,1994,32(04):675-686. |
[22] | HUI-MING CHENG;HIROYUKI ENDO;TOSHIHIRO OKABE .Graphitization Behavior of Wood Ceramics and Bamboo Ceramics as Determined by X-Ray Diffraction[J].Journal of porous materials,1999(3):233-237. |
[23] | 蒋文举,江霞,朱晓帆,金燕.微波处理对活性炭孔隙结构的影响[J].林产化学与工业,2004(01):21-24. |
[24] | Hiroyuki Fujimoto .Theoretical X-ray scattering intensity of carbons with turbostratic stacking and AB stacking structures[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(8):1585-1592. |
[25] | 任俊;沈健;卢寿慈.颗粒分散科学与技术[M].北京:化学工业出版社,2005 |
[26] | 肖敏,杜续生,孟跃中,龚克成.热处理条件对氧化石墨结构和导电性能的影响[J].新型炭材料,2004(02):92-96. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%