以三(2-二甲氨基乙基)胺(Me6TREN)作为配体,CuCl作为引发剂,苯乙烯(St)和4-乙烯基吡啶(VP)单体进行原子转移自由基聚合(ATRP)得到了两亲聚合物P(S-VP),凝胶色谱仪(GPC)测得的分子量分布曲线为单峰,其分子量为7 153,分布系数为1.217,St单元和VP单元的比值为1∶1.15.P(S-VP)修饰碳管后在水、氯仿以及丙酮中的分散性能均得到改善.
参考文献
[1] | 朱蕙,刘世勇,潘全名,段宏伟,江明.窄分布两亲性嵌段共聚物的合成及其胶束化行为研究[J].高等学校化学学报,2002(01):138-142. |
[2] | Polyxeni M et al.Mutlifunctional ATRP initiators:synthesis of four arm star homo-polymers of methylmethacry late and graft copolymer of polystyrene and oly(t-butylmethacrylate)[J].Journal of Polymer Science Part A: Polymer Chemistry,2001,39(05):650-655. |
[3] | Matyjaszewski K.;Gaynor SG.;Pyun J. .Preparation of hyperbranched polyacrylates by atom transfer radical polymerization, 4 - The use of zero-valent copper[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,1998(12):665-670. |
[4] | Yang ZG;Yuan JJ;Cheng SY .Self-assembling of biocompatible BAB amphiphilic triblock copolymers PLL(Z)-PEG-PLL(Z) in aqueous medium[J].European Polymer Journal,2005(2):267-274. |
[5] | Liu RCW;Pallier A;Brestaz M;Pantoustier N;Tribet C .Impact of polymer micro structure on the self-assembly of amphiphilic polymers in aqueous solutions[J].Macromolecules,2007(12):4276-4286. |
[6] | 杨子刚,袁建军,程时远.两亲嵌段共聚物溶液自组装新进展[J].功能高分子学报,2003(02):287-292. |
[7] | Yiyong H et al.Lodge self-assembly of block copolymer micelles in an Ionic liquid[J].American Chemical Society,2006,128(08):2745-2750. |
[8] | 赵群,倪沛红.PH/温度响应的两亲性嵌段共聚物的研究[J].化学进展,2006(06):768-779. |
[9] | Dayananda K;Pi BS;Kim BS;Park TG;Lee DS .Synthesis and characterization of pH/temperature-sensitive block copolymers via atom transfer radical polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(3):758-762. |
[10] | George J P B et al.Non-heme Iron(Ⅱ) complexes containing tripodal tetradentate nitrogen ligands and their application in alkane oxidation catalysisinorg[J].Chemistry-A European Journal,2005,44(22):8125-8134. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%