3-硝基-4-多氟烷氧基苯甲酸酯类液晶的合成和相变研究

液晶与显示 , 2002, 17(2): 92-97. doi: 10.3969/j.issn.1007-2780.2002.02.003

3-硝基-4-多氟烷氧基苯甲酸酯类液晶的合成和相变研究

王侃 ^1, , 刘克刚 ^2, , 李衡峰 ^3, , 闻建勋 ^4,

1.中国科学院,上海有机化学研究所,上海,200032

2.中国科学院,上海有机化学研究所,上海,200032

3.中国科学院,上海有机化学研究所,上海,200032

4.中国科学院,上海有机化学研究所,上海,200032

基金项目: 国家自然科学基金(29974038)

关键词：液晶 , 相变性质 , 合成 , 氟碳链

Synthesis and Mesomorphic Properties of Mesogens Bearing 3-nitro-4-polyfluoroalkoxybenzoate Group

设计并合成了一类新型的3-硝基-4-多氟烷氧基苯甲酸 4-[4-n-庚氧基-2,3-二氟亚苯基乙炔基]苯酚酯液晶, 并通过差示扫描量热法(DSC)和偏光显微镜对其相变行为进行了观察和测试, 发现当氟碳链较短时, 化合物呈现向列相和近晶A相, 氟碳链增长后, 化合物只呈现近晶A相.

参考文献

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3-硝基-4-多氟烷氧基苯甲酸酯类液晶的合成和相变研究

Synthesis and Mesomorphic Properties of Mesogens Bearing 3-nitro-4-polyfluoroalkoxybenzoate Group

参考文献