欢迎登录材料期刊网

材料期刊网

高级检索

通过在3,5-二羟基苯甲醇分子中的双酚基基团上引入双肉桂酰酯光敏基团的酯化反应,合成了一类新型的分子顶部为羟基极性基团,整个分子构型类似于树枝状的光敏小分子化合物.将此种光敏材料配成一定浓度的溶液,旋涂在玻璃基板上成膜,经过线性偏振紫外光辐照后发生交联反应,制备成光控取向膜.以此种取向膜制成向列相液晶的平行液晶器件,在偏光显微镜下观察,发现取得了均一、稳定的取向效果,并且该取向膜具有良好的热稳定性能.

参考文献

[1] Seo D S,Araya K,Yoshida N,et al.Effect of the polymer tilt angle for generation of pretilt angle in nematic liquid crystal on rubbed polyimide surfaces[J].Jpn.J.Appl.Phys.,1995,34(4B):L503-L506.
[2] Matsuda H,Seo D S,Yoshida N,et al.Estimation of the static electricity and optical retardation produced by rubbing poly imide and polyamide films with different fabrics[J].Mol.Cryst.Liq.Cryst.,1995,264:23-28.
[3] Schadt M,Seiberle H,Schuster A.Optical patterning of multidomain liquid-crystal displays with wide viewing angles[J].Nature,1996,381 (6579):212-215.
[4] Liu J,Liang X,Tang H,et al.Allyl p-fluor cinnamate grafted polysiloxane photoalignment films polymerized under linear polarized UV light[J].Thin Solid Films,2001,384(2):212-214.
[5] Akiyama H,Iimura Y.Azimuthal anchoring properties of nematic liquid crystalonUV-exposedpolyimidelayers[J].Jpn.J.Appl.Phys.,2002,41(5A):L521-L523.
[6] 梁兆颜,宣丽,杨柏梁,等.光控取向弱锚定表面的液晶分子排列[J].液晶与显示,2000,15(1):53-59.
[7] 闫石,梁兆颜,黄锡珉.聚甲基丙烯酸肉桂酰氧基乙酯的光控取向研究[J].液晶与显示,1997,12(4):237-243.
[8] Egerton P L,Pitts E,Reisner A.Photocycloaddition in solid poly(vinyl cinnamate).The photoreactive polymer matrix as an ensemble of chromophore sites[J].Macromolecules,1981,14(1):95-100.
[9] Akiyama H,Momose M,Ichimura K,et al.Surface-selective modification of poly(vinyl alcoho1)films with azobenzenes for inplane alignment photocontrol of nematic liquid crystals[J].Macromolecules,1995,28(1):288-293.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%