当前液晶自适应光学系统还不能满足校正大气湍流频率(＞40 Hz)的要求,这主要受限于LCOS器件的响应速度(10～20 ms)和位相调制量超过1λ的系统要求.研制新型快速高双折射率向列相液晶材料是解决这一问题的根本方案.本文从分子结构上探讨了影响液晶粘度和双折射率的一般规律.在此基础之上,设计了两种低粘度、高双折射率的液晶分子.通过使用AM1半经验量子化学算法进行了模拟计算,预测了所设计的液晶材料的Δn和Δε值.模拟结果说明,这两种结构的液晶材料能够很好地满足自适应系统的要求.
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