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引入双轴向列相液晶分子模型,采用分叉理论和二粒子集团理论来确定双轴向列相液晶中的Landau点,分别得出了液晶各向同性相向单轴向列相转变对分子双轴性参数的依赖曲线.在Landau点处,分叉理论、二粒子集团理论和平均场理论得到的分子双轴性参数λ取值是相同的,而约化温度t的取值不同,由二粒子集团理论得到的约化温度值更为精确.二粒子集团理论考虑了近邻分子间的短程关联,由此可知在双轴向列相液晶的研究中考虑近邻分子间的短程关联是非常必要的.

参考文献

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