采用低频倒置扭摆内耗仪对组分为Pb(Zr0.7Ti0.3)O3(PZT73)和Pb(Zr0.3Ti0.7)O3(PZT37)的两种陶瓷的内耗Q-1及振动频率的平方f2(正比于材料的剪切模量G)与温度的关系进行了测定。在纯三角相的PZT73陶瓷中发现两个内耗峰。高温内耗峰PM起源于材料的顺电-铁电相变,低温内耗峰P1本质上是一个宽化的Debye峰,可归因于氧空位作用下的畴壁振荡弛豫。对纯四方相的PZT37陶瓷,除了P1和PM峰外,在P1与PM峰之间另有内耗峰P2,这与900畴附近的氧空位团簇的弛豫有关,其特征可用描述强关联系统的关联态模型(Couplingmodel)描述。
The internal friction Q- 1 and the square of vibration frequency f 2(proportional to shear modulus G) were measured as a function of temperature on undoped Pb(Zr0.7Ti0.3)O3 (PZT73) and Pb(Zr0.3Ti0.7) O3 (PZT37) ceramics from 200C to 5000C. Experiments were performed on an inverted torsion pendulum at low frequencies (1~ 5Hz) .Two internal friction peaks were found in pure rhombohedral PZT73 ceramics. The high temperature peak PM, which appears at the Curie temperature, originates from the para- ferroelec-tric phase transition. The low temperature peak P1 is a broadened Debye peak in nature, and it is contri-buted to the oscillation damping of the domain walls locked by the oxygen vacancies. For the pure tetrago-nal PZT37 ceramics, another peak P2,which appears between P1 and PM,can be well described by the coup-ling model. It is thought to be related with the relaxation of oxygen vacancy clusters near the 900 domains.
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