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采用离子束增强沉积的方法,改变氧分压,在硅基体表面制备出了不同组分及不同取向的氧化钛薄膜。采用XRD,掠角衍射以及XPS分析方法对薄膜的成分、结构和取向进行了分析,并通过RBS分析计算出了薄膜的O/Ti比。实验结果发现,所制备的氧化钛薄膜为具有一定择优取向的多晶膜,薄膜内TiO、Ti2O3和TiO2共同存在。当氧分压低于8.4×10-4Pa时,氧化钛薄膜的成分以TiO为主,且TiO的取向随氧分压的增加从(220)向(031)转变,氧分压对薄膜取向的影响较大。当氧分压高于8.6×10-4Pa时,氧化钛薄膜的成分以具有(100)择优取向的金红石型TiO2为主,含有少量其他结构的TiO2和低价Ti,其成分及取向相对较为稳定,对氧分压的变化不敏感。

A series of titanium oxide thin films have been synthesized on silicon wafers by ion beam en-hance deposition at different O2 pressure. X-ray Photo-electron Spectroscopy, X-ray diffraction (XRD), glancing angle diffraction and Rutherford backscattering spectroscopy(RBS) were used to analyse the composition, structure and orientation of the film. It was found that: 1) The film is polycrystal-line with Ti2+, Ti3+, Ti4+coexist. 2) When O2 pressure is lower than 8.4× 10-4 Pa, the main composition of the film is TiO that preferred orientation changed from (220) to (031) with the increase of O2 pressure. 3) When the O2 pressure is above 8.6× 10-4 Pa, rutile TiO2 with a preferred orientation of (100) is foundto be the major composition of the film.

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