采用离子束增强沉积的方法,改变氧分压,在硅基体表面制备出了不同组分及不同取向的氧化钛薄膜。采用XRD,掠角衍射以及XPS分析方法对薄膜的成分、结构和取向进行了分析,并通过RBS分析计算出了薄膜的O/Ti比。实验结果发现,所制备的氧化钛薄膜为具有一定择优取向的多晶膜,薄膜内TiO、Ti2O3和TiO2共同存在。当氧分压低于8.4×10-4Pa时,氧化钛薄膜的成分以TiO为主,且TiO的取向随氧分压的增加从(220)向(031)转变,氧分压对薄膜取向的影响较大。当氧分压高于8.6×10-4Pa时,氧化钛薄膜的成分以具有(100)择优取向的金红石型TiO2为主,含有少量其他结构的TiO2和低价Ti,其成分及取向相对较为稳定,对氧分压的变化不敏感。
A series of titanium oxide thin films have been synthesized on silicon wafers by ion beam en-hance deposition at different O2 pressure. X-ray Photo-electron Spectroscopy, X-ray diffraction (XRD), glancing angle diffraction and Rutherford backscattering spectroscopy(RBS) were used to analyse the composition, structure and orientation of the film. It was found that: 1) The film is polycrystal-line with Ti2+, Ti3+, Ti4+coexist. 2) When O2 pressure is lower than 8.4× 10-4 Pa, the main composition of the film is TiO that preferred orientation changed from (220) to (031) with the increase of O2 pressure. 3) When the O2 pressure is above 8.6× 10-4 Pa, rutile TiO2 with a preferred orientation of (100) is foundto be the major composition of the film.
参考文献
[1] | Sprague Robet W;Hickey Carolyn F;Hodgkinson Ian J .The influence of argon ion bombardment on form birefringence in thin films of titanium[J].Journal of Applied Physics,1992,71(07):3201-3203. |
[2] | Wicaksana Dwi;Kobayashi Akihiko;Kinbara Akira.Process effects onstruvtural properties of TiO2 thin films by reacture sputtering (4),1479- 1462[J].Journal of Vacuum Science and Technology,1992:A10. |
[3] | Feng Zhang;Zhihong Zheng;Yu Chen;Yinjum Mao Xianghuai Liu .Effect of Xe+ bombardment on the formation of highly-oriented rutile-type titanium oxide films[J].Thin Solid Films,1998,312:1-3. |
[4] | Plapprty EC;Dahmen KH;Hanert R;Erst KH .Deposition of amorphous titanium oxide films using alkoxy(pyrazolylborate) titanium (IV) compounds[J].Chemical Vapor Deposition,1999,5(02):79-85. |
[5] | Rizzo A;Mirenghi L;Puirini A;Scaglione S .Synthesis of stoichiometric titania films by oxygen ion assistance of growing titanium[J].Surface and Coatings Technology,1997,91:153-157. |
[6] | Oh W S;Xu C;Kim D Y;Goodman D W .Preparation and characterization of expitxial titanium oxide films on Mo(100)[J].Journal of Vacuum Science and Technology,1997,A15(03):1710-1716. |
[7] | Feng Zhang;Zhihong Zheng;Xingzhao Ding .Highly oriented ruffle-type TiO films synthesized by ion beam enhanced deposition[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,1997(4):1824-1827. |
[8] | Zhang F;Zheng Z;Chen Y;Liu X;Chen A;Jiang Z .In vivo investigation of blood compatibility of titanium oxide films.[J].Journal of biomedical materials research, Part B. Applied biomaterials,1998(1):128-133. |
[9] | 王华馥;吴自勤.固体物理方法[M].北京:高等教育出版社,1990 |
[10] | Feng Zhang;Zhihong Zheng;Yu Chen;Duo Liu Xianghuai Liu .Study on the effect of ion beam bombardment during deposition on prefered orientation in rutile- type titanium dioxide films[J].Journal of Applied Physics,1998,15:4101-4105. |
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