制备了一种新型非线性光学晶体:二甲亚砜合硫氰酸汞锰(分子式:MnHg(SCN)4(C2H6SO)2,简称MMTD).用热重法、差热分析法、差示扫描量热法、热机械分析法、分光光度法和红外光谱研究了它的热学和光学性质.MMTD晶体具有较好的物理化学稳定性.在27℃时,它的比热为699.5 J/mol·℃.晶体的热膨胀系数为α1=5.33×10-5/℃,α2=4.51×10-5/℃,α3=3.10×10-5/℃.MMTD晶体的截止波长为375nm;透光波段为375-2560 nm.MMTD晶体在标准紫光波长404nm的透过率为44.18%,高于硫氰酸汞锰(MMTC)晶体.
参考文献
[1] | 许东.双重基元结构模型与金属有机络合物高效倍频晶体的研究[J].人工晶体,1987(01):1. |
[2] | Long N J .Organometallic Compounds for Nonlinear Optical - the Search for En - light - enment[J].Angewandte Chemie International Edition,1995,34:21. |
[3] | You X Z .Chemical studies on the nonlinear optics of coordination compounds[J].Journal of Photochemistry and Photobiology A:Chemistry,1997,106:85. |
[4] | Mendez- Rojas M A;Bodige S G;Watson W H .Structure and properties of potential nonlinear optical materials[J].Journal of Chemical Crystallography,1999,29:1255. |
[5] | Jiang MH.;Fang Q. .Organic and semiorganic nonlinear optical materials[J].Advanced Materials,1999(13):1147-1151. |
[6] | Hurst S K;Lucas N T;Cifuentes M P et al.Organometallic complexes for nonlinear optics Part 23.Quadratic and cubic hyperpolarizabilities of acetylide and vinylidene complexes derived from protected and free formylphenylacetylenes[J].Journal of Organometallic Chemistry,2001,633:114. |
[7] | Wang X Q;Yu W T;Xu D et al.Poly[ [bis(dimethylsulfoxide - κO) tris - (thiocyanato - κN)manganese(Ⅱ) ] - 1 - thiocyanato - κ2N: S - mercury(Ⅱ[J].Acta Crystallographica,2000,C56:418. |
[8] | 中本一雄.无机和配位化合物的红外和拉曼光谱[M].,1991 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%