采用溶胶-凝胶法和传统的固相反应法相结合,制备了双层钙钛矿结构锰氧化物La2-2xSr1+2xMn207较宽掺杂范围内(0.2≤x≤0.6)系列单相样品,并测量了各样品的X射线衍射谱(XRD)和扩展X射线吸收精细结构(EXAFS)谱.通过对XRD的分析证实样品均为Sr3Ti2O7型四方结构,空间群为I4/mmm,同时发现晶格参数a随掺杂量x的变化几乎不变,而c随x的增加则明显减小.通过对EXAFS的分析和研究得到MnO6八面体中c轴方向的Mn-O键长和JahnTeller畸变量△JT随掺杂浓度x的变化,发现在最佳掺杂浓度x=0.33附近,J-T畸变最大,显示出La2-2xSr1+2xMn207(0.2≤x≤0.6)系列锰氧化物的磁电性能与畸变量△JT密切相关.
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