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用多晶薄膜晶粒-晶界两相结构模型,考虑晶格畸变和载流子对晶界势垒区的隧穿机制,在10~100℃范围内,模拟了离子束增强沉积(IBED)VO2多晶薄膜的相变.模拟结果显示,由于晶粒中间隙位置氩的存在,使VO2晶格畸变,导致了薄膜中部分晶粒的相变温度降低,使IBED VO2薄膜在48℃开始由半导体相向金属相转变.

参考文献

[1] Goodenough J B .The two component of the crystallographic transition in VO2[J].Journal of Solid State Chemistry,1971,3:490-499.
[2] 李金华,袁宁一,陈王丽华,林成鲁.用离子束增强沉积从V2O5粉末制备高热电阻温度系数VO2薄膜[J].物理学报,2002(08):1788-1792.
[3] W. Burkhardt;T. Christmann;B. K. Meyer;W. Niessner;D. Schalch;A. Scharmann .W- and F-doped VO_2 films studied by photoelectron spectrometry[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(2):229-235.
[4] P. Jin;S. Nakao;S. Tanemura .Tungsten doping into vanadium dioxide thermochromic films by high-energy ion implantation and thermal annealing[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(1/2):151-158.
[5] Songwei Lu;Lisong Hou;Fuxi Gan .Surface analysis and phase transition of gel-derived VO_2 thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(12):40-44.
[6] Nilgun Ozer;Sevsen Sabuncu;John Cronin .Electrochromic properties of sol-gel deposited Ti-doped vanadium oxide film[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(12):201-206.
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