欢迎登录材料期刊网

材料期刊网

高级检索

使用乙烯-乙烯醇共聚物/聚吡咯复合膜和聚醚基氨酯/LiClO4电解质制成全固态电致变色器件.当加上1.0~2.5V的直流电压时,器件颜色由黄色变成棕(蓝)色.详细讨论了器件的UV/VIS光谱变化、掺杂/不掺杂过程的响应时间以及电解质浓度对变色过程的影响.结果显示电致变色器件在800nm时,发生掺杂/不掺杂过程变化有短的响应时间和大的透过率差.

参考文献

[1] 周馨我;张公正;范广裕.功能材料学[M].北京:北京理工大学出版社,2002:376-377.
[2] Skotheim T A.Handbook of Conducting Polymers[M].New York:Marcel Dekker,1986:673.
[3] Park S M;Ko J M;Rhee H W et al.Morphology And Electrochemical Properties Of Polypyrrole Films Prepared In Aqueous And Monaqueous Solvents[J].Journal of the Electrochemical Society,1990,137:905-909.
[4] Li S;White H S .Synthesis of Conducting Polymer Composite Fibers in Electrochemical Flow Cells[J].Journal of the Electrochemical Society,1993,140:2473-2476.
[5] Lien M;Smyrl W H;Morita M .Cation and anion insertion in separate processes in poly (pyrrole) composite films[J].Journal of Electroanalytical Chemistry,1993,309:333-340.
[6] Baker C K;Qiu Y J;Reynolds J R .Electrochemicallyinduced charge and mass transport in polypyrrole/poly(styrene sulfonate) molecular composites[J].Journal of Physical Chemistry,1991,95:4446-4452.
[7] Otero T F;Bengoechea M .In situ absorption-reflection study of polypyrrole composites-switching stability[J].Electrochimica Acta,1996,41:1871-1876.
[8] 浦鸿汀,黄平.电致变色器件用聚合物电解质材料的研究进展[J].功能材料与器件学报,2005(02):127-133.
[9] Lee K H;Park J K .Ion conductivity studies of blends of poly (methyl methacrylate)-g-poly (ethylene glycol) and poly (ethylene glycol) complexed with LiCF3SO3[J].Journal of Polymer Science Part A:Polymer Chemistry,1996,34:1427-1433.
[10] Paoli M A;Casalbore-Miceli G;Girotto E M et al.All polymer solid state electrochromic devices[J].Electrochimica Acta,1999,44:2983-2991.
[11] Maria M S;Sandra C B .Study of novel lithium saltbased,plasticized polymer electrolytes[J].Journal of Power Sources,2002,111:52-57.
[12] Maria M S;Sandra C B;Michael J S .Characterization of solid polymer electrolytes based on poly (trimethylenecrabonte) and lithium tetrafluoroborate[J].Electrochimica Acta,2004,49:1887-1891.
[13] Mitsuhiro Shibata;Ken-Ichi Kawashita;Ryutoku Yosomiya;Zhang Gongzheng .Electrochromic properties of polypyrrole composite films in solid polymer electrolyte[J].European Polymer Journal,2001(5):915-919.
[14] Asai T .Influence of matrix polymer used for poly (3-methythiophene)-based composite films on electrochromic properties[D].Narashino:Department of Industrial Chemistry,Chiba Institute of Technology in Japan,2000.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%