以分散聚合法制得的聚苯乙烯微球为种子,以1,2-二氯乙烷为溶胀剂、己二酸二辛脂(DOA)为助溶胀剂、二乙烯基苯(DVB)为交联剂及甲基丙烯酸(MAA)或丙烯酸(AA)为水溶性功能性单体,采用活性溶胀聚合法成功制得大粒径由羧基修饰的交联聚苯乙烯微球.研究了溶胀剂种类及活性种球粒径对交联聚苯乙烯羧基微球最大平均粒径及粒径分布的影响,并对交联聚苯乙烯羧基微球进行了红外谱图分析及热失重(TGA)分析,结果制得最大粒径为25.0um的交联聚苯乙烯羧基微球,热分解温度为273.8℃.
参考文献
[1] | Jing-She Song;Leonid Chagal;Mitchell A.Winnik .Monodisperse Micrometer-Size Carboxyl-Functionalized Polystyrene Particles Obtained by Two-Stage Dispersion Polymerization[J].Macromolecules,2006(17):5729-5737. |
[2] | Song, SN;Zhang, W;Hu, ZQ;Zhang, ZC .Monodisperse micrometer-size carboxyl-functionalized polystyrene particles obtained by two-stage radiation-induced dispersion polymerization[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2009(1/3):1-8. |
[3] | A.Yu.Menshikova;T.G.Evseeva;Yu.O.Skurkis .Monodisperse carboxylated polystyrene particles:synthesis,electrokinetic and adsorptive properties[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(4):1417-1425. |
[4] | Zhang HT;Huang H;Lv R;Chen M .Micron-size crosslinked microspheres bearing carboxyl groups via dispersion copolymerization[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2005(1/3):217-221. |
[5] | Jean M.J.Frechet;Ithaca,N.Y;Ken Hosoya .Kyoto,Japan Preparation of surface-functional polymer particles[P].US Pat.5306561 |
[6] | 王胜广;王琛;王洛礼;于洁.种子溶胀法制备由羧基修饰的交联聚苯乙烯羧基微球[J].稀有金属 |
[7] | Ugelstad J;Mórk PC;Kaggerud KH;T.Ellingsen and Berge A .Sintef,Nth,Trondheim.Swelling of oligomer polymer particles:New methods of preparation of emulsions and polymer dispersions[J].Advances in Colloid and Interface Science,1980,13:101-140. |
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