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以BaCO3和TiO2粉末为原料,采用固相反应法合成Ba2Ti9O20的粉体,并以此粉体为主要原料添加适量的分散剂、粘结剂及塑性剂,采用流延法制备Ba2Ti9O20陶瓷膜片.研究了不同种类和配比的溶剂、不同种类和含量的分散剂对Ba2Ti9O20流延浆料的流变特性的影响.结果表明,当选用异丙醇和甲苯(体积比为75:25)为溶剂,固含量Ba2Ti9O2054wt%,分散剂蓖麻油0.5wt%,粘结剂聚乙烯醇缩丁醛5wt%,塑性剂聚乙二醇5wt%时,流延浆料的流变性能较好,浆料的粘度为9.1Pa.S.

参考文献

[1] J.-A. Lee;J.-H. Lee;J.-J. Kim .Low-temperature sintering and microwave dielectric characteristics of Ba_2Ti_9O_(20) ceramics[J].Journal of the European Ceramic Society,2006(10/11):2111-2115.
[2] Huang CL.;Lion CT.;Wu CC.;Weng MH. .Low temperature sintering and microwave dielectric properties of Ba2Ti9O20 ceramics using glass additions[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2000(14/15):2445-2456.
[3] 姚尧,赵梅瑜,王依琳,吴文骏.固相合成制备单相Ba2Ti9O20粉体及陶瓷[J].硅酸盐学报,1998(06):796-801.
[4] 周建民,王亚东,王双喜,黄国权.制备电子陶瓷基片用的流延成型工艺[J].硅酸盐通报,2010(05):1114-1118.
[5] 李冬云,乔冠军,金志浩.流延法制备陶瓷薄片的研究进展[J].硅酸盐通报,2004(02):44-47.
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[7] 朱海奎,周洪庆,刘敏,韦鹏飞,宁革.CaO-B2O3-SiO2系LTCC流延生料带研制[J].电子元件与材料,2009(09):17-19.
[8] JANTUNEN Heli;HU Tao;UUSIMAKI Antti et al.Tape casting of ferroelectric,dielectric,piezoelectric and ferromagnetic materials[J].Journal of the European Ceramic Society,2004,24(06):1077-1081.
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