采用浸渍还原法分别制备了两种不同铂含量的Pt/C纳米催化剂和Pt - Mn/C、Pt - Co/C纳米合金催化剂,利用XRD和TEM技术对催化剂的粒径大小、晶体结构和晶格常数进行表征,并对四种催化剂进行了循环伏安、线性扫描伏安和电流-时间测试.结果表明:四种催化剂的平均粒径均在10nm以下,且Pt - Mn/C、Pt - Co/C两种合金催化剂的粒径均小于Pt/C催化剂;四种催化剂均为面心立方晶体结构;与Pt/C催化剂相比,两种合金催化剂的晶格常数有所减小,且结晶度较低.电化学性能测试表明,两种Pt合金催化剂较相同Pt载量的纯Pt催化剂具有更高的还原峰电位和更大的还原峰电流,其中Pt - Co/C催化剂的还原峰电位和峰电流最大;在催化剂稳定性方面,两种Pt合金催化剂要优于两种纯Pt催化剂.
参考文献
[1] | Jia Ma .A comprehensive review of direct borohydride fuel cells[J].Renewable & sustainable energy reviews,2010(1):183-199. |
[2] | B.H. Liu;Z.P. Li .Current Status And Progress Of Direct Borohydride Fuel Cell Technology Development[J].Journal of Power Sources,2009(2):291-297. |
[3] | Cenk Celik;Fatma Gul Boyaci San;Halil Ibrahim Sarac .Effects Of Operation Conditions On Direct Borohydride Fuel Cell Performance[J].Journal of Power Sources,2008(1):197-201. |
[4] | Umit B. Demirci .Direct borohydride fuel cell: Main issues met by the membrane-electrodes-assembly and potential solutions[J].Journal of Power Sources,2007(2):676-687. |
[5] | Wee J H .A comparison of sodium borohydride as a fuel for proton exchange emembrane fuel cells and for direct borohydride fuel cells[J].Journal of Power Sources,2006,155(02):329-339. |
[6] | H.Y. Qin;Z.X. Liu;W.X. Yin;J.K. Zhu;Z.P. Li .A Cobalt Polypyrrole Composite Catalyzed Cathode For The Direct Borohydride Fuel Cell[J].Journal of Power Sources,2008(2):909-912. |
[7] | Doo H J;Chang H L;Chang S K et al.Performance of a direct methanol polymer electrolyte fuel cell[J].Journal of Power Sources,1998,71(01):169-173. |
[8] | Leon C P C;Walsh F C;Pletcher D et al.Direct borothyride fuel cells[J].Journal of Power Sources,2006,155(02):172-181. |
[9] | R. W. Reeve;P. A. Christensen;A. Hamnett;S. A. Haydock;S. C. Roy .Methanol tolerant oxygen reduction catalysts based on transition metal sulfides[J].Journal of the Electrochemical Society,1998(10):3463-3471. |
[10] | Thorsten Schilling;Michael Bron .Oxygen reduction at Fe-N-modified multi-walled carbon nanotubes in acidic electrolyte[J].Electrochimica Acta,2008(16):5379-5385. |
[11] | Hiroyuki Uchida;Yohsuke Mizuno;Masahiro Watanabe .Suppression of Methanol Crossover and Distribution of Ohmic Resistance in Pt-Dispersed PEMs under DMFC Operation[J].Journal of the Electrochemical Society,2002(6):A682-A687. |
[12] | Hui Yang;Walter Vogel;Claude Lamy;Nicolas Alonso-Vante .Structure and Electrocatalytic Activity of Carbon-Supported Pt-Ni Alloy Nanoparticles Toward the Oxygen Reduction Reaction[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(30):11024-11034. |
[13] | U. A. Paulus;A. Wokaun;G. G. Schere;T. J. Schmidt;V. Stamenkovic;N. M. Markovic;P. N. Ross .Oxygen reduction on high surface area Pt-based alloy catalysts in comparison to well defined smooth bulk alloy electrodes[J].Electrochimica Acta,2002(22/23):3787-3798. |
[14] | Yuan W;Scott K;Cheng H .Fabrication and evaluation of Pt-Fe alloys as methanol tolerant cathode materials for direct methanol fuel cells[J].Journal of Power Sources,2006,163(01):323-329. |
[15] | 刘世斌,杨春英,张忠林,段东红,郝晓刚,李一兵.薄壳层核壳型Ni/Pt纳米粒子的制备及电催化性能[J].无机材料学报,2012(01):95-101. |
[16] | Wang X H;Huang H;Tim H et al.Thermal stabilities of nanoporous metallic electrodes at elevated temperatures[J].Journal of Power Sources,2008,175(01):75-81. |
[17] | Gurau B;Viswanathan R;Liu R et al.Structural and electrochemical characterization of binary,ternary,and quaternary platinum alloy catalysts for methanol el ectro-oxidation[J].Journal of Physical Chemistry B,1998,102(49):9997-10003. |
[18] | Jalan V M;Taylor E J .Importance of interatomic spacing in catalytic reduction of oxygen in phosphoric acid[J].Journal of the Electrochemical Society,1983,130(11):2299-2302. |
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