本文用两种不同的方法对同期制备的不同浓度的苯、甲苯、二甲苯及其混合气和摩托车尾气三类样品分别进行了对比实验.实验验证了多光子电离所得实验数据的可靠性及其测量精确性,同时可以看出多光子电离方法所具有的快速、实时在线和多组分同时探测的优越性.
参考文献
[1] | Boesl U, Neusser H J, Schlag E W. Two-photon ionization of polyatomic molecules in a mass spectrometer [J]. Z.Naturforsch., 1978, 33A: 1546~1548 |
[2] | Antonov V S, Knyazev I N, Letokhov V S et al. Stepwise laser photoionization of molecules in a mass spectrometer:a new method for probing and detection of polyatomic molecules [J]. Opt. Lett., 1978, 3(2): 37~39 |
[3] | Boesl U. Multiphoton excitation and mass selective ion detection for neutral and ion spectroscopy [J]. J. Phys.Chem., 1991, 95(8): 2949~2962 |
[4] | Hager J W, Wallace S C. Two-laser photoionization supersonic jet mass spectrometry [J]. Anal. Chem., 1988,60(1): 5~10 |
[5] | Weickhardt C, Boesl U, Schlag E W. Laser mass spectrometry for time-resolved multicomponent analysis of exhaust gas [J]. Anal. Chem., 1994, 66(7): 1062~1069 |
[6] | Heger H, Zimmermann R, Dorfner et al. On-line emission analysis of polycyclic aromatic hydrocarbons down to pptv concentration levels in the flue gas of an incineration pilot plant with a mobile resonance-enhanced multiphoton ionization time-of-flight mass spectrometer [J]. Anal. Chem., 1999, 71(1): 46~57 |
[7] | Boesl U. Laser mass spectrometry for environmental and industrial chemical trace analysis [J]. J. Mass Spectrom.,2000, 35(3): 289~304 |
[8] | Castaldi M J, Senkan S M. Real time, ultrasensitive monitoring of air toxics by laser photoionization time-of-flight mass spectrometry [J]. Journal of the Air & Waste Management Association, 1998, 48:77~81 |
[9] | Loepfe M, Burtscher H, Siegmann H C. Analysis of combustion products using time-of-flight mass spectrometry [J]. Water, Air and Soil Pollution, 1993, 68(1~2): 177~184 |
[10] | Franzen J, Frey R, Nagel H. Fast monitoring of motor exhaust components by resonant multiphoton ionization and time-of-flight mass spectrometry [J]. Journal of Molecular Structure, 1995, 347:143~151 |
[11] | Boesl U, Nagel H, Weickhardt C et al. Vehicle exhaust emission time-resolved multicomponent analysis by laser mass spectrometry [M]. The Encyclopedia of Environmental Analysis and Remediation, 1998, 5000~5022 |
[12] | Boesl U, Nagel H, Weickhardt C et al. Calibration method for the quantitative analysis of gas mixture by means of multiphoton ionization mass spectrometry [J]. Rev. Sci. Instrum., 1993, 64(12): 3482~3486 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%