在230～440 nm波段,研究了复合物Mg+-S2(CH3)2的光解离光谱.此波段内的复合物光诱导产物的质谱揭示,存在着非反应猝灭产物Mg+和反应产物Mg+-SCH3.反应产物来源于Mg+离子插入S-S化学键,导致复合物解离的过程.复合物的光解离光谱由三个对应于离子Mg+(32P←32S)跃迁的谱峰构成.由量化计算中的CIS方法所获得的吸收谱理论值与实验吻合地较好.
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