报道了自主研制的光电离-离子迁移谱装置的基本结构和性能.采用10.6 eV Kr灯为电离源,以苯为检测样品,对迁移电场电压、离子门电压和脉冲宽度参数进行优化,得到最佳装置参数为离子门脉冲宽度0.15 ms,离子门电压80 V,迁移区电压2153 V.使用指数稀释方法制备样品浓度,获得了离子迁移谱检测苯的标准曲线,对苯的检测限为400 ppt,检测线性动态范围跨越三个数量级.
参考文献
[1] | Eiceman G A,Preston D,Tiano G,et al.Quantitative calibration of vapor levels of TNT,RDX,and PETN using a diffusion generator with gravimetry and ion mobility spectrometry[J].Talanta,1997,45:57-74. |
[2] | Deng Qiaolin,Li Hu,Han Haiyan,et al.Aromatic compounds separation and detection by tandem gas chromatography and photoionization ion mobility spectrometry[J].Chinese Journal of Quantum Electronics(量子电子学报),2011,28:12-18 (in Chinese). |
[3] | Huang Guodong,Han Haiyan,Jia Xiande,et al.Discharge ion mobility spectrometry of ketonic organic compounds[J].Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27:833-836(in Chinese). |
[4] | Karpas Z,Pollevoy Y,Melloul S.Determination of bromine in air by ion mobility spectrometry[J].Anal.Chim.Acta,1991,249:503-507. |
[5] | Han Haiyan,Wang Hongmei,Jiang Haihe,et al.Corona discharge ion mobility spectrometry of ten alcohols[J].Chinese J.Chem.Phys.,2009,22:605-610. |
[6] | Han Haiyan,Jia Xiande,Huang Guodong,et al.Ion mobility spectrometry for the isomeric volatile organic compounds[J].Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27:1925-1928(in Chinese). |
[7] | Revercomb H E,Mason E A.Theory of plasma chromatography gaseous electrophoresis-review[J].Anal.Chem.,1975,47:970-983. |
[8] | Mason E A.Ion Mobility:Its Role in Plasma Chromatography[M].New York:Plenum Press,1984:43-93. |
[9] | Han Haiyan,Huang Guodong,Jing Sunping,et al.Determination of alcohol compounds using corona discharge ion mobility spectrometry[J].J.Environ.Sci-China,2007,19:751-755. |
[10] | Lubman D M,Kronick M N.Plasma chromatography with laser-produced ions[J].Anal.Chem.,1982,54:1546-1551. |
[11] | Shumate C.Electrospray ion mobility spectrometry[J].Trac-Trend Anal.Chem.,1994,13:104-109. |
[12] | Bohrer B C,Mererbloom S I,Koeniger S L,et al.Biomolecule analysis by ion mobility spectrometry[J].Annu.Rev.Anal.Chem.,2008,1:293-327. |
[13] | Sabo M,Palenik J,Kucera M,et al.Atmospheric pressure corona discharge ionisation and ion mobility spectrometry/mass spectrometry study of the negative corona discharge in high purity oxygen and oxygen/nitrogen mixtures[J].Int.J.Mass Spectrom.,2010,293(1-3):23-27. |
[14] | http://www.cheric.org/research/kdb/[OL]. |
[15] | Okano K.Theory of ion-extraction time from a plasma by a static electric-field[J].J.Nucl.Sci.Technol.,1992,29:601-607. |
[16] | Kanu A B,Gribb M M,Hill H H.Predicting optimal resolving power for ambient pressure ion mobility spectrometry[J].Anal.Chem.,2008,80:6610-6619. |
[17] | Siems W F.Measuring the resolving power of ion mobility spectrometers[J].Anal.Chem.,1994,66:4195-4201. |
[18] | Leasure C S,Fleischer M E,Anderson G K,et al.Photoionization in air with ion mobility spectrometry using a hydrogen discharge lamp[J].Anal.Chem.,1986,58:2142-2147. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%