近红外量子剪裁能够有效地提高硅太阳能电池的效率.稀土元素种类繁多,能级丰富,常被用于制作近红外量子剪裁发光材料.研究者们用适当的方法制成发光材料之后,测量材料的吸收光谱,激发光谱和发射光谱.根据这些数据计算得到材料的量子效率.其中Tb3+-Yb3+离子对备受关注.Tb3+吸收紫外-可见光,通过协同能量传递把能量传递给Yb3+离子.Yb3+离子跃迁辐射出1000 nm左右的近红外光.该波段的光子能够被硅太阳能电池吸收利用.Tb3+-Yb3+离子对在不同掺杂浓度,不同基质中得到的量子效率不同.
参考文献
[1] | Chen Xiaobo,Li Song,Zou Qiuyan,et al.Two-photon near-infrared quantum cutting of Yb3+ in YVO4 host through cooperate energy transfer[J].Chinese Journal ofQuantum Electronics(量子电子学报),2014,1:125 (in Chinese).,2014. |
[2] | Xu Xurong,Su Mianzeng.Luminescence and Luminescence Materials(发光学与发光材料)[M].Chemical Industry Press,2004 (in Chinese).,2004. |
[3] | Vergeer R,Vlugt T J H,Kox M H F,et al.Quantum cutting by cooperative energy transfer in YbxY1-xPO4:· Tb3+[J].Phys.Rev.B (Condensed Matter and Materials Physics),2005,71:14111-14119.,2005. |
[4] | Zhang Q Y,Yang C H,Pan Y X.Cooperative quantum cutting in one-dimensional YbxGd1-xA13(BO3)4:Tb3+ nanorods[J].Appl.Phys.Lett.,2007,90:2.,2007. |
[5] | Huang X Y,Zhang Q Y.Efficient near-infrared quantum cutting in Zn2SiO4:Tb3+,Yb3+ thin-film[J].Journal of Applied Physics,2009,105(5):053521-053521-4.,2009. |
[6] | Yuan J L,Zeng X Y,Zhao J T,et al.Energy transfer mechanisms in Tb3+,Yb3+ co-doped Y2O3 down conversion phosphor[J].Journal of Physics D-Applied Physics,2008,41:10.,2008. |
[7] | Zhang Q H,Wang J,Zhang G G,et al.UV photon harvesting and enhanced near-infrared emission in novel quantum cutting Ca2BO3Cl:Ce3+,Tb3+,Yb3+ phosphor[J].Journal of Materials Chemistry,2009,19,38:7088-7092 (in Chinese).,2009. |
[8] | Liu X,Ye S,Qiao Y,et al.Cooperative down conversion and near-infrared luminescence of Tb3+,Yb3+ co-doped lanthanum borogermanate glasses[J].Appl.Phys.B-Lasers and Optics,2009,96,1:51-55.,2009. |
[9] | Lakshminarayana G,Qiu J R.Near-infrared quantum cutting in RE3+/Tb3+ (RE=Pr,Tb,Tm):GeO2-B2O3ZnO-LaF3 glasses via down conversion[J].Journal of Alloys and Compounds,2009,481 (1-2):582-589.,2009. |
[10] | 林辉,周圣明,侯肖瑞,李宇焜,李文杰,滕浩,贾婷婷.Tb3+,Yb3+共掺Y2O3透明陶瓷的制备及其下转换近红外发光研究[J].光学学报,2010(12):3547-3551. |
[11] | CHEN Jing-Xin,YE Song,WANG Xi,QIU Jian-Rong.Cooperative Quantum Cutting of Nano-Crystalline BaF2:Tb3+, Yb3+ in Oxyfluoride Glass Ceramics[J].中国物理快报(英文版),2008(06):2078-2080. |
[12] | Chen Xiaobo,Yang Guojian,Ding Fenfang,et al.Cooperaive down conversion in Tb(0.7) Yb(5):FOV oxyfluoride nanophase vitroceramics[J].Spectroscopy and Spectral Analysis(光谱学与光谱分析),2011,31:11 (in Chinese).,2011. |
[13] | Chen Daqin,Yu Yunlong,Wang Yuansheng,et al.Down-conversion in Yb3+:TbF3 nanocrystals embedded glass ceramics[J].Phys.Chem.C,2009,113:6406-6410.,2009. |
[14] | Liao Jinsheng,Su Zhenyu,Zhou Dan,et al.Hydrothermal method and luminescent properties of Cao.8-2x(YbxTb0.1Nao.1+x)2xWO4 near-infrared down conversion phosphor[J].Chinese Journal of Inorganic Chemistry(无机化学学报),2013,29:11 (in Chinese).,2013. |
[15] | Zhou Jiajia,Teng Y,Qiu Jianrong,et al.Enhanced downconversion luminescence by co-doping Ce3+ in Tb3+-Yb3+ doped borate glasses[J].Chemical Physics Letters,2010,486(4-6):116-118.,2010. |
[16] | Zhang Liang,He Qingli,Hu Xiaoyun,et al.Preparation Tb3+,Yb3+ doped Y2O3 of luminescent powders and near-infrared quantum cutting research[J].Spectroscopy and Spectral Analysis(光谱学与光谱分析),2014,34(1):23-26 (in Chinese).,2014. |
[17] | Wu Xiaojie,Zhang Zhenzhong,Meng Fanzhi,et al.Core-shell-like Y2O3:【Tb3+-Yb3+,Li+】/CdZnS heterostructure synthesized by super-close-space sublimation for broadband down-conversion[J].The Royal Society of Chemistry,2014,6(9):4745-4749.,2014. |
[18] | Chen Daqin,Wang Yuansheng,Hong M C.Lanthanide nanomatetials with photon management characteristics for photovoltaic application[J].Nano Energy,2012,1(1):73-90.,2012. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%